نتایج جستجو برای: Huisgen 1,3-dipolar cycloaddition

تعداد نتایج: 343729  

2013
K. Ajay Kumar

The 1,3-Dipolar cycloaddition reactions are the classic reaction in modern synthetic organic chemistry. The concept of these reactions was introduced by Huisgen and his co-workers in the early 1960’s. 1,3-Dipolar cycloaddition reactions are simple but powerful tool for the construction of five membered heterocycles such as isoxazoles, isoxazolines, pyrazoles, pyrazolones, 1,2,4-oxadiazolines et...

In this protocol, we report a novel approach for the synthesis of a new class of heterocyclic 1H-1,2,3-triazole-modified peptidomimetic compounds. The process consists of an Ugi four-component condensation reaction of amines, an isocyanide, an aldehyde and acids followed by a Huisgen 1,3-dipolar cycloaddition reaction with an azide group in the presence of a catalytic amount of CuSO4</...

Journal: :Chemical communications 2011
Miriam M Unterlass Edgar Espinosa Fernande Boisson Franck D'Agosto Christophe Boisson Katsuhiko Ariga Ivan Khalakhan Richard Charvet Jonathan P Hill

An α-[Cu(II)-porphyrin]-polyethylene was synthesized for the first time using copper catalyzed 1,3-dipolar azide-alkyne Huisgen cycloaddition yielding highly colored moiety-substituted polyethylene.

Journal: :Chemical communications 2005
Dirk T S Rijkers G Wilma van Esse Remco Merkx Arwin J Brouwer Hans J F Jacobs Roland J Pieters Rob M J Liskamp

Multivalent dendrimeric peptides were synthesized via a microwave-assisted Huisgen 1,3-dipolar cycloaddition between azido peptides and dendrimeric alkynes in yields ranging from 46 to 96%.

Journal: :Chemical communications 2005
A J Ton Dirks Sander S van Berkel Nikos S Hatzakis Joost A Opsteen Floris L van Delft Jeroen J L M Cornelissen Alan E Rowan Jan C M van Hest Floris P J T Rutjes Roeland J M Nolte

Biohybrid amphiphiles have been prepared from terminal azide functionalised polystyrene and an alkyne functionalised peptide or protein via a Cu(I) catalysed Huisgen [3 + 2] dipolar cycloaddition reaction.

Journal: :Bioorganic & medicinal chemistry letters 2007
Martijn Verdoes Ulrik Hillaert Bogdan I Florea Myra Sae-Heng Martijn D P Risseeuw Dmitri V Filippov Gijsbert A van der Marel Herman S Overkleeft

The synthesis of three acetylene functionalized BODIPY dyes is described. These dyes are used to fluorescently modify an azido functionalized epoxomicin analogue employing the Huisgen 1,3-dipolar cycloaddition, resulting in a panel of fluorescent epoxomicin derived proteasome probes.

Journal: :Chemical communications 2008
Julien Iehl Rossimiriam Pereira de Freitas Béatrice Delavaux-Nicot Jean-François Nierengarten

A Th-symmetrical C60 hexakis-adduct bearing 12 peripheral azide groups has been prepared and used to produce functionalized derivatives by the copper mediated Huisgen 1,3-dipolar cycloaddition of azides and alkynes.

Journal: :Chemical communications 2010
Yi Jiang Jia-Bin Guo Chuan-Feng Chen

A novel bifunctionalized [3]rotaxane based on a triptycene-derived macrotricyclic host was conveniently synthesized. On the basis of the [3]rotaxane, a linear main-chain poly[3]rotaxane was further obtained by the highly efficient Huisgen 1,3-dipolar cycloaddition.

Journal: :Chemical communications 2010
Jean-François Nierengarten Julien Iehl Vincent Oerthel Michel Holler Beatriz M Illescas Antonio Muñoz Nazario Martín Javier Rojo Macarena Sánchez-Navarro Samy Cecioni Sébastien Vidal Kevin Buffet Maxime Durka Stéphane P Vincent

Fullerene hexakis-adducts bearing 12 peripheral carbohydrate moieties have been prepared by grafting sugar derivatives onto the fullerene core through the copper mediated Huisgen 1,3-dipolar cycloaddition of azides and alkynes.

Journal: :Molbank 2021

The 1,2,3-triazole is a well-known biologically active pharmacophore constructed by the copper-catalyzed azide–alkyne cycloaddition. We herein reported synthesis of 4-amino-7-chloro-based [1,2,3]-triazole hybrids via Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition 4-azido-7-chloroquinoline with an alkyne derivative acetaminophen. compound was fully characterized Fourier-transform infrared (FT...

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