the gas separation performance of commercial ceramic titania and hybrid silica (hybsi®) membranes was assessed using the gas permeation and permporometry methods. results indicated that the hybsi® membranes have a hybrid surface containing regions covered by a polymeric matrix and others with inorganic pores. these membranes have high h2 selectivity, which increases significantly with temperatu...

mfi-type zeolite membranes (zsm-5) were prepared on α-alumina tubular supports and tested for separation of h2/co mixtures. the effect of pressure and temperature on h2 and co flows and selectivity was investigated. the best results in this work were obtained with a zsm-5 membrane prepared over a porous α-alumina tube seeded with zeolite nanocrystals synthesized with microwave technique. in thi...

This study investigates the separation based on adsorption of the binary gas mixture of hydrogen withbiogas (gases: CO2, CH4, O2, N2) and inert gases (gases: He, Ne, and Ar) using single-walled ((7,7), (15,15),(29,29), (44,44), (58,58) and (73,73) SWBNNTs), double-walled ((11,11)@(15,15), (7,7)@(22,22) DWBNNTs)and triple walled ((8,8)@(11,11)@(15,15) and (7,7)@(15,15)@(22,22) ...

mil-53-cu has been synthesized hydrothermally and has been used for the first time for gas separation. mil-53-cu shows adsorption capacities of 8.1, 0.7 and 0.5 m.mol/g, respectively, for ch4, co2 and h2 at 30 bar and 298 k. the high ch4 adsorption capacity of mil-53-cu maybe attributed to the high pore volume and large number of open metal sites. the high selectivity for ch4 over co2 (11.5) an...

In this work, the main aspects regarding the permeation of mixtures containing CO2 and permanent gases such as H2 , N2 and CH4 through zeolite membranes have been investigated, focusing on the description of the mass transport mechanisms taking place inside the pores. First, a brief overview about the performance of the main zeolite membranes used in gas separation (e.g. DDR, CHA, AEI, FAU, etc...

This work shows the application of a validated mathematical model for gas permeation at high temperatures focusing on demonstrated scale-up design for H2 processing. The model considered the driving force variation with spatial coordinates and the mass transfer across the molecular sieve cobalt oxide silica membrane to predict the separation performance. The model was used to study the process ...

In this work, three different graphene-based materials, namely graphite oxide (GrO), thermally reduced graphite oxide (T-RGrO) and ascorbic acid multi-phase reduced graphene oxide (AMP-RGO), were synthesized and used to produce mixed matrix membranes (MMM) based on Matrimid®5218 for as separation. From the samples produced, a complete set of characterization was performed including XRD, FTIR, T...

equilibrium adsorption property of multi-walled carbon nanotubes with oh group was studied using experimental design for the adsorption of co2 , ch4 and h2 . the effect of temperature, pressure, their binary interactions and quadratic terms were studied for adsorption capacity of nanotubes and the results were analyzed by the face centered central composite design method and analysis of varianc...

Equilibrium adsorption property of multi-walled carbon nanotubes with OH group was studied using experimental design for the adsorption of CO2 , CH4 and H2 . The effect of temperature, pressure, their binary interactions and quadratic terms were studied for adsorption capacity of nanotubes and the results were analyzed by the face centered central composite design method and analysis of varianc...

Light isotopes separation, such as (3)He/(4)He, H2/D2, H2/T2, etc., is crucial for various advanced technologies including isotope labeling, nuclear weapons, cryogenics and power generation. However, their nearly identical chemical properties made the separation challenging. The low productivity of the present isotopes separation approaches hinders the relevant applications. An efficient membra...