نتایج جستجو برای: External electron donor
تعداد نتایج: 552319 فیلتر نتایج به سال:
copolymerization of ethylene and propylene was investigated using a 4th generation phthalate ziegler-natta catalyst in normal hexane in a buchi reactor. the effects of different mole fractions of [al]/[ti], [si]/[al] and various amounts of hydrogen on productivity and weight percent of ethylene on the product, were studied. in the copolymerization reactions, tri-isobutyl aluminum (tibal) was us...
in this investigation the effect of external field on the electron density of nanostructures of cds, cdse, cdte, gaas and polymeric structure of three, four, five and six units of cds as a kind of nanosolar cells has been studied theoretically. as modeling this system in nanodimension, molecular structures has used. specific properties of molecular structures permit us to consider different sym...
this is a report on the study of high melt flow, highly isotactic polypropylene homopolymer synthesized in liquid monomer using a fifth generation ziegler-natta catalytic system. at highest catalyst productivity, the response of thecatalyst to hydrogen as chain transfer is studied. melt flow rate is controlled by hydrogen as chain transfer from 0.4 to 300 g/10min with changing the amount of hyd...
in this research we have studied the effect of some transition-metals (cu, ag and au) substitutions on two-electron reduction potential of flavins by application of dft method. all geometries have been optimized at blyp level of theory and “6-31+g** + lanl2dz” mixed basis set. the frequency job at the same method and basis sets has been performed to obtain gibbs free energy of compounds. it h...
Dopamine functionalized carbon nanoparticles (CNPs) that can act as efficient photoinduced electron donor-acceptor systems depending on the pH of the medium have been synthesized. In acidic media, dopamine on CNPs exists as hydroquinone and serves as an electron donor while under alkaline conditions the corresponding quinone form of dopamine serves as a strong electron acceptor. Application of ...
We report a general strategy for fine-tuning the bandgap of donor-acceptor-donor based organic molecules by modulating the electron-donating ability of the donor moiety by changing the benzochalcogenophene donor groups from benzothiophenes to benzoselenophenes to benzotellurophenes. These molecules show red-shifts in absorption and external quantum efficiency maxima from sulfur to selenium to t...
Two thioacetyl-terminated ferrocene-anthraquinone donor-acceptor molecules with different pi-electron conjugative units have been synthesized via a series of Stille and Sonagashira reactions. Their photochemical and electrochemical properties before and after addition of an organic acid are investigated, indicating that these complexes are sensitive to external perturbation of protonation, lead...
Highly efficient exciplex systems incorporating a heptazine derivative () as an electron acceptor and 1,3-di(9H-carbazol-9-yl)benzene () as an electron donor are developed. An organic light-emitting diode containing 8 wt% : as an emitting layer exhibits a maximum external quantum efficiency of 11.3%.
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