Motivated by our recent proposition on the possibility of using dielectric continuum models to interpret experimental measurements of solvation dynamics in room temperature ionic liquids [J. Phys. Chem. A 110, 8623 (2006)], some detailed simulation studies are performed to test the validity of our proposition. From these simulation studies, it seems to be justified that an extended Debye-Hückel...

the solubility of co2 in the primary, secondary, tertiary and sterically hindered amine aqueous solutions at various conditions was studied. in the present work, the modified kent-eisenberg (m-ke), the extended debye-hückel (e-dh) and the pitzer models were employed to study the solubility of co2 in amine aqueous solutions. two explicit equations are presented to evaluate the concentration of h...

a r t i c l e i n f o a b s t r a c t The photoionization processes of excited hydrogen atoms in plasma environments are investigated using the method of complex coordinate rotation. The standard Debye–Hückel model and modified Debye– Hückel model are adopted to describe the plasma screening effects. The photoionization cross sections of plasma-embedded excited hydrogen atoms varied with differ...

According to thermodynamic principle, the critical relative humidity of electrolytes is closely related to their solubility. The authors explored the relationship theoretically and calculated the critical relative humidity of 21 electrolytes in the light of Raoult's law, modified Debye-Hückel model and extended non-random two liquid (NRTL) model from their solubility. The results indicate that ...

In this report, a molecular Debye-Hückel theory for ionic fluids is developed. Starting from the macroscopic Maxwell equations for bulk systems, the dispersion relation leads to a generalized Debye-Hückel theory which is related to the dressed ion theory in the static case. Due to the multi-pole structure of dielectric function of ionic fluids, the electric potential around a single ion has a m...

The extended universal quasichemical (UNIQUAC) model is a thermodynamic model for solutions containing electrolytes and nonelectrolytes. The model is a Gibbs excess function consisting of a Debye–Hückel term and a standard UNIQUAC term. The model only requires binary ion-specific interaction parameters. A unique choice of standard states makes the model able to reproduce solid–liquid, vapor–liq...

Coulomb corrections to the equation of state of degenerate matter are usually described by Debye-Hückel theory; however, recent studies have considered modifications of thermodynamic quantities which are caused by the interactions of charged particles beyond the Debye-Hückel approximation. Based on the weakly-coupled plasma limit, the formulae for the physical properties of non-ideal effects on...

Nuclear electron capture rate from continuum in an astrophysical plasma environment (like solar core) is calculated using a modified Debye–Hückel screening potential and the related non-Gaussian q-distribution of electron momenta. For q = 1 the well-known Debye–Hückel results are recovered. The value of q can be derived from the fluctuation of number of particles and temperature inside the Deby...

The solubility of KNO3 in the mixed solvent (water 85%+methanol 15%) were determined by using solvent evaporating method at different temperatures (25, 30, 40, 50, 60 ;C). In addition the equilibrium constant of ion pair formation, KIP, for K+NO3 – ion-pair on the basis of Fuoss contact ion pair model was calculated. Upon choosing the extended Debye-Hückel model for estimating the mean activity...