The paper presents some different methods for a chemical exothermic batch reactor control. A mathematical model including reaction kinetics was used to simulate a real process. The process chemical reaction is strongly exothermic so the in-reactor temperature is rising very fast due to reaction component dosing. Thus, the temperature control is necessary. The system is nonlinear because of chem...

Density fingering of exothermic autocatalytic fronts in vertically oriented porous media and Hele-Shaw cells is studied theoretically for chemical reactions where the solutal and thermal contribution to density changes have opposite signs. The competition between these two effects leads to thermal plumes for ascending fronts. The descending fronts behave strikingly differently as they can featu...

Ah&act-This paper is devoted to the temperature control and the stabilization under input constraints of exothermic chemical reactors. We first consider a reactor in which a single and exothermic reaction takes place and design state feedback controllers to achieve the global and robust stabilization under input constraints of the reactor. Then, we extend these results to a general class of exo...

The aim of this paper is to present simulation of model predictive control of chemical exothermic semi-batch reactor model, while the MPC controller uses an artificial neural network as a predictor. A first order chemical reaction is considered to be running in the reactor. The reaction is strongly exothermic so the in-reactor temperature is rising very fast due to reaction component dosing. Th...

Glass/ceramic composite coatings were prepared on 40Cr steel matrix by thermo-chemical reaction with fly ash and a small amount of SiO2, Al2O3, MgO, and albite as main raw materials. On this basis, adding 10% Al-TiO2-B2O3 exothermic system, the morphology, phase, thermal shock resistance, and corrosion resistance of the coating were tested, and the influence of exothermic system on the structur...

The hybrid CBS-QB3 electronic structure approach is used to calculate the reaction energetics for decomposition reactions of radicals formed from UV radiation of the polymer poly(methyl methacrylate) (PMMA). Relative to the photon created radical species, the decarboxylation reaction to form CO2 is exothermic whereas the reaction to form CO is endothermic. For degradation of the polymer in low-...

The self-propagating foaming process of porous Al-Ni intermetallics was investigated. Aluminum and nickel powders were blended, and titanium and boron carbide powders were added as reactive exothermic agents. The blended powder was extruded to make a rod-shape precursor. Only one end of the rod precursor was heated to ignite the reaction. The reaction propagated spontaneously throughout the pre...