Given the challenges to life at low pH, an analysis of inorganic sulfur compound (ISC) oxidation was initiated in the chemolithoautotrophic extremophile Acidithiobacillus caldus. A. caldus is able to metabolize elemental sulfur and a broad range of ISCs. It has been implicated in the production of environmentally damaging acidic solutions as well as participating in industrial bioleaching opera...

The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for integrated gasification combined cycle power generation plants. For coal-derived synthesis gases with low sulfur content, direct air injection can be utilized to selectively oxidize the hydrogen sulfide present into elemental sulfur via the reaction H2S...

abstract date palm, phoenix dactylifera, is one of the most important horticultural crops in iran. the most soils in iran, especially those cultivated with palm, are calcareous with high ph. the high ph of soil causes reduction of nutrient elements absorption. findings of researches show that application of elemental sulfur along with tiobacillus bacteria in soil, due to sulfur oxidation, reduc...

The modified Claus process is the major technology for the recovery of elemental sulfur from hydrogen sulfide. The chemical reactions that can occur in the reaction furnace are numerous and many byproducts such as carbon disulfide and carbon carbonyl sulfide are produced. These compounds can often contribute from 20 to 50% of the pollutants and therefore, should be hydrolyzed in the catalytic c...

Elemental sulfur exists as a variety of forms in natural systems, from dissolved forms (noted as S8 (aq.)) to bulk elemental sulfur most stable as α-S8 (bulk) (but existing in at least 180 different allotropes and polymorphs). Elemental sulfur can form via a number of biotic and abiotic processes, many of which begin with S-S bonding of practically unlimited length, forming chains and rings of ...

The influence of sodium chloride on dissolution of chalcopyrite and surface sulfur speciation during bioleaching of chalcopyrite with the extreme thermophile Acidianus manzaensis YN-25 was studied. The addition of sodium chloride accelerated the dissolution of chalcopyrite by reducing the accumulation of elemental sulfur layers on the mineral surface, resulting in an increase in the concentrati...

Several bioreactor systems are used for biological treatment of hydrogen sulfide. Among these, airlift bioreactors are promising for the bioconversion of hydrogen sulfide into elemental sulfur. The performance of airlift bioreactors is not adequately understood, particularly when directly fed with hydrogen sulfide gas. The objective of this paper is to investigate the performance of an airlift ...

Polysulfides formed through the breakdown of elemental sulfur or other sulfur compounds were found to be reduced to H(2)S by the hyperthermophilic archaebacterium Pyrococcus furiosus during growth. Metabolism of polysulfides by the organism was dissimilatory, as no incorporation of S-labeled elemental sulfur was detected. However, [S]cysteine and [S]methionine were incorporated into cellular pr...

The sulfur-binding protein of Thiobacillus ferrooxidans ATCC 23270 was investigated. The protein composition of the bacterium's cell surface changed according to the culture substrate. Sulfur-grown cells showed greater adhesion to sulfur than iron-grown cells. The sulfur-grown cells synthesized a 40-kDa surface protein which was not synthesized by iron-grown cells. The 40-kDa protein had thiol ...