The anti-tumour natural product cis-solamin has been shown to occur as a mixture two of tetra-epimeric diastereoisomers 1A and 1B, whereas solamin (6) was isolated as a single diastereoisomer; the biosyntheses of 1A/B and 6 are likely to involve enzyme-mediated cyclohydrations of the bis-epoxide acetogenins anti-diepomuricanin A2 and syn-diepomuricanin A1 respectively, where addition of water o...

This research describes photo degradation of direct red 81(5-solamin) in the presence of zinc oxide nano-sized catalyst supported on granule glass under UV light irradiation. The effects of some parameters such as various pH and different atmosphere on photo degradation efficiency were studied. After various experiments it was revealed that among various atmospheres, at neutural medium, oxygen ...

A novel fluorescence resonance energy transfer (FRET) system containing a two-photon absorbing dye and a nile red chromophore has been synthesized. Upon two-photon excitation by laser at 815 nm this molecule displays efficient energy transfer from the two-photon absorbing dye to the nile red moiety, with an 8-fold increase in emission compared to the model compound. Similarly, single-photon exc...

in this study, the potential of biosorbent obtained from silk maze, was investigated for the batch biosorption of direct red 81 (dr 81) in aqueous solution. the effects of temperature, biosorbent amount, contact time, initial dye concentration and ultrasonic irradiation were also evaluated. furthermore, experimental equilibrium and kinetics data were fitted by langmuir and freundlich isotherms ...

1 Département de Psychologie, Université de Montréal, Montreal, Quebec, Canada 2 Centre de recherche de l’Institut universitaire de gériatrie de Montréal (CRIUGM), Montreal, Quebec, Canada 3 Department of Psychology, Columbia University, Montreal, Quebec, Canada 4 Department of Anaesthesiology, Harvard Medical School, Boston, MA, USA 5 Department of Stomatology, Faculty of Dentistry, Université...

in this work, efficiency and performance of hazelnut shells (hs) adsorbent was examined for the removal and recovery of direct red 12b (dr12b) from wastewater. the absorbance of dr12b was measured spectrophotometrically at λmax=523 nm before and after adsorption of dr12b. the maximum removal was 99.8% for 30 mg l –1 ofdr12b concentration on 0.3 gr hs adsorbent. acidic ph was favourable for the ...