Palladium nanoparticles supported on carbon black powder (Vulcan XC-72) nanocomposite (Pd/C) are synthesized as the catalyst for the anodic oxidation of glucose for use in a direct glucose alkaline fuel cell (DGAFC). Characterization of the catalyst is carried out using physical and electrochemical methods. It is observed that Palladium nanoparticles are uniformly dispersed onto the carbon blac...

in this study, a sodalite nanozeolite was synthesized and characterized by x-ray diffraction (xrd) and scanning electronic microscopy (sem). following the morphology evolution of the sodalite nanozeolite in the sem images illustrates the formation of the spherical particle with a size between 60 and 80 nm. then, carbon paste electrode (cpe) was modified by sodalite nanozeolite and ni2+ ions. th...

Exploiting electrocatalysts with high activity for glucose oxidation is of central importance for practical applications such as glucose fuel cell. Pt-decorated nanoporous gold (NPG-Pt), created by depositing a thin layer of Pt on NPG surface, was proposed as an active electrode for glucose electrooxidation in neutral and alkaline solutions. The structure and surface properties of NPG-Pt were c...

High-Performance Alkaline Direct Methanol Fuel Cell using a Nitrogen-Postdoped Anode Report Title A commercial PtRu/C catalyst postdoped with nitrogen demonstrates a significantly higher performance (?10–20?% improvement) in the anode of an alkaline direct methanol fuel cell than an unmodified commercial PtRu/C catalyst control. The enhanced performance shown herein is attributed at least parti...

The paper focuses on the conductivity of the fuel cell electrolyte in a membraneless glucose-fueled alkaline fuel cell. The electrolyte conductivity is interpreted using simple physical models, considering either the empirical behavior of the solution’s viscosity, or the consideration of ions and molecules colliding in solutions. The conductivity is expressed as a function of KOH and glucose co...

Recently, increasingly attentions have been paid to the electro-oxidation of ethanol in alkaline media in the context of using ethanol as a fuel in anion-exchange membrane fuel cell. Alkaline media presents several advantages compared to acidic media. It has been found that the electrocatalytic activity for etanol oxidation in alkaline media is much higher than that in acidic media [1]. Further...

in present research work, homogeneous anion exchange membranes based on polysulfone (qapsfs) were prepared via chloromethylation, amination and alkalization. in amination step, trimethylamine and n,n,n',n'-tetramethyl-1,6-hexanediamine were used as amination and crosslinking agents, respectively. the chloromethylated polysulfone was characterized by 1hnmr spectroscopy and chloromethylation degr...

nanotechnology has opened up new opportunities for the design of nanoscale electronic devices suitable for developing high-performance biofuel cells. glucose-based biofuel cells as green energy sources can be a powerful tool in the service of small-scale power source technology as it provides a latent potential to supply power for various implantable medical electronic devices. by using physiol...

Six different electron mediators were immobilized on the activated carbon (AC) anode and their effects on performance of a direct glucose alkaline fuel cell were explored. 2-hydroxy-1, 4-naphthoquinone (NQ), methyl viologen (MV), neutral red (NR), methylene blue (MB), 1, 5-dichloroanthraquinone (DA) and anthraquinone (AQ) were doped in activated carbon (AC), respectively, and pressed on nickel ...

direct electron transferring of glucose oxidase was investigated   on reduced graphene and graphene oxide templates. the direct electrochemistry   glucose oxidase on   graphene showed a cyclic voltammograms corresponding to the fad/fadh 2   redox couple with an anodic, cathodic and formal potential of -430, -460 and   -445 mv, respectively in 0.1 m phosphate buffer solution and air saturated   ...