diopside (CaO·MgO·2SiO2) and wollastonite (CaO·SiO2) glass-ceramics, forming ∼60% crystal phase and ∼40% albite-like Na2O·Al2O3·6SiO2) residual glass were studied. Two other diopside glass-ceramics with higher Na2O and Al2O3 content were also investigated. The phase formation was estimated by DTA, XRD and pycnometry, while the densification process was evaluated by porosity variations, ilatomet...

Data determined using a multianvil press are given for liquidus phase relations in the system diopside – forsterite – enstatite (CaMgSi2O6 – Mg2SiO4 – MgSiO3) and extend for a limited distance into the larger ternary system diopside – forsterite – quartz at 5.1 GPa. In the system diopside–enstatite, which cuts across the system diopside – forsterite – quartz and divides it into two smaller tern...

Wollastonite (CaSiO3) and diopside (CaMgSi2O6) silicate ceramics have been widely investigated as highly bioactive materials, suitable for bone tissue engineering applications. In the present paper, highly porous glass-ceramic foams, with both wollastonite and diopside as crystal phases, were developed from the thermal treatment of silicone polymers filled with CaO and MgO precursors, in the fo...

Ah&act-The tem~ratu~-de~ndent thermal expansivities of melts along the join ano~hite-diopside have been determined on glassy and liquid samples using a combination of calorimetry, dilatometry, and Pt double bob Archimedean densitometry. Supercooled liquid volumes and molar thermal expansivities were determined using scanning calorimetric and dilatometric measurements of properties in the glass ...

Introduction: Knowledge of how crystals grow is of fundamental importance for interpreting textures observed in meteorites. However, data on crystal growth of rock-forming silicates for a very small degree of undercooling (< 1°C) are extremely rare. Recently [1], it was demonstrated that these very small degrees of undercooling could be experimentally approached by studying the kinetic of Oswal...

Silicates are well known for their bioactivity, here we are reporting the bioactivity of diopside (CaMgSi2O6) synthesized by sol-gel combustion process by using citric acid and succinic acid as a mixed fuel. The phase formation of the prepared sample was confirmed by powder X-Ray Diffraction. In-vitro bioactivity of the diopside in conjugation with biopolymer chitin in various proportions were ...

The formation of intragranular pores, induced by diopside crystallization in diopside–albite glasses, was highlighted in a previous study and here confirmed by SEM observation. The sinter-crystallization kinetics of four glass compositions, labelled G1, G2, G3 and G2-Cr, characterized by the formation of induced crystallisation porosity, PCR, was investigated. The activation energies of crystal...