Structure-activity relationships of a nanostructured Cu/ZrO2 catalyst for the steam reforming of methanol (MSR) were investigated under reaction conditions by in situ X-ray absorption spectroscopy (XAS) and X-ray diffraction (XRD) combined with on-line mass spectrometry (MS). Temperature programmed activation by reduction in hydrogen or by reduction in a mixture of methanol and water (feed) was...

The development of active catalysts for carbon dioxide (CO2) hydrogenation to methanol is intimately related the creation effective metal-oxide interfaces. In this work, we investigated how order addition copper and zinc on zirconia influences catalytic properties, activity selectivity toward methanol. Regarding conversion production, which promoter (zinc) was atomically deposited after impregn...

Ternary Cu/ZnO/metal oxide catalysts are prepared through the co-precipitation method under strict control of parameters like pH, calcination conditions, and precipitation temperature in a systematic manner. The metal oxides applied in this study consist of Al2O3, ZrO2, La2O3 and Ce2O3. The distinction of this work in comparison with similar research is a comprehensive investigatation of the ca...

CuO-ZnO-ZrO2 catalysts were synthetized by co-precipitation synthesis. Copper content in was kept constant (30 wt% of Cu °) and ZnO gradually substituted ZrO2 the support to have a greater understanding support’s effect find optimal ZnO/ZrO2 ratio. These fully characterized then tested methanol synthesis via CO2 hydrogenation. The effects reaction temperature GHSV on catalytic behavior investig...

nanocomposite of zro2/zno was prepared under ultrasonic irradiation by sol gel process from directly mixing zirconium and zinc gels. the mixture was placed under ultrasonic irradiation for 2 hours. after the aging time and filtration of the reaction mixture, the filtrated composite gel was calcinated at 500 °c for 3h in furnace. the precursor gels of zirconium and zinc were prepared from dissol...

The aim of the present study was to evaluate the antibiofilm activity against Enterococcus faecalis, compressive strength. and radiopacity of Portland cement (PC) added to zirconium oxide (ZrO2), as radiopacifier, with or without nanoparticulated zinc oxide (ZnO). The following experimental materials were evaluated: PC, PC + ZrO2, PC + ZrO2 + ZnO (5%), and PC + ZrO2 + ZnO (10%). Antibiofilm act...

Coumarins play an important role in drug development with diverse biological applications. Herein, we present the synthesis of coumarin through Pechmann reaction by using zirconia-based heterogeneous catalysts (ZrO2-TiO2, ZrO2-ZnO, and ZrO2/cellulose) in a solvent-free condition at room temperature. ZrO2-TiO2, ZrO2-ZnO, and ZrO2/cellulose were identified through spectroscopic techniques such as...

zno and zro2 photo catalysts were synthesized by sol-gel auto combustion method. the products were characterized by x-ray diffraction (xrd) and scanning electron microscopy (sem). structural and morphological properties of nano particles were investigated and the average crystalline size of zno and zro2 was obtained 44 and 51 nm, respectively. also, photo catalytic degradation of nitro phenol f...