100-nm-thick Cu layers were grown on MgO(001) substrates by ultra-high vacuum magnetron sputter deposition at substrate temperatures Ts ranging from 40 to 300 °C. X-ray diffraction ω−2θ scans, ω-rocking curves, and pole figures show that layers grown at Ts=40 and 100 °C are complete single crystals with a cube-on-cube epitaxial relationship with the substrate: (001)Cu||(001)MgO with [100]Cu||[1...

Various structures of Cu (50 nm)/Ru (2 nm)/MgO (0.5-3 nm)/Ta (2 nm)/Si were prepared by sputtering and electroplating techniques, in which the ultra-thin trilayer of Ru (2 nm)/MgO (0.5-3 nm)/Ta (2 nm) is used as the diffusion barrier against the interdiffusion between Cu film and Si substrate. The various structures of Cu/Ru/MgO/Ta/Si were characterized by four-point probes for their sheet resi...

in the present study, the effects of calcium doping on the performance of the co-precipitated cu-mgo catalysts prepared with different calcium loadings in the selective hydrogenation of furfuraldehyde were investigated. the results proved that the addition of this promoter had a remarkable impact on the catalytic performance. the conversion of furfuraldehyde enhanced up to 83% and the furfuryl ...

Three-dimensional atom-probe (3DAP) microscopy has been applied to the study of segregation at ceramic/metal (C/M) interfaces. In this article, results on the MgO/Cu(X) (where X = Ag or Sb) systems are summarized. Nanometer-size MgO precipitates with atomically clean and atomically sharp interfaces were prepared in these systems by internal oxidation. Segregation of the ternary component (Ag or...

Interfacial properties of 5 nm MgO(001)/7 nm Fe(001)/1.8 nm MgO(001)/t nm Cu-phthalocyanine (CuPc) hybrid multilayers with t = 0, 1, 7, and 10 were investigated by using x-ray photoemission spectroscopy (XPS). Rather sharp interfacial properties were observed in the CuPc films grown on an epitaxial MgO/Fe/MgO(001) trilayer than a MgO/Fe(001) bilayer. This work suggests a new way to improve devi...

Single-crystal Cu(001) layers, 4-1400 nm thick, were deposited on MgO(001) with and without a 2.5-nm-thick TiN(001) buffer layer. X-ray diffraction and reflection indicate that the TiN(001) surface suppresses Cu-dewetting, yielding a 4 lower defect density and a 9 smaller surface roughness than if grown on MgO(001) at 25 C. In situ and low temperature electron transport measurements indicate th...

In the present study, the effects of calcium doping on the performance of the co-precipitated Cu-MgO catalysts prepared with different calcium loadings in the selective hydrogenation of furfuraldehyde were investigated. The results proved that the addition of this promoter had a remarkable impact on the catalytic performance. The conversion of furfuraldehyde enhanced up to 83% and the furfuryl ...

Superconductingg thickk films (200µm ~300µm) of YBCO have been fabricated successfully on MgO substrates by a new approach. The precursor powders (YBa 2 Cu 3 O 7-δ (Y123) + 0.1molY 2 BaCuO 5 (Y211)) are placedd between two MgO (10mm×10mm)slicesto formsandwichstructure.TheYBCOthickk films have been obtainedd from the precursors by modifiedd melt growth process. Resistance measurementsofYBCOthick...

In the present study, the effects of calcium doping on the performance of the co-precipitated Cu-MgO catalysts prepared with different calcium loadings in the selective hydrogenation of furfuraldehyde were investigated. The results proved that the addition of this promoter had a remarkable impact on the catalytic performance. The conversion of furfuraldehyde enhanced up to 83% and the furfuryl ...

Local density functional theory ~LDFT! calculations, within the plane-wave-pseudopotential framework, are performed for the $222%MgO/Cu polar interface, with the objective of elucidating the atomic and electronic structure of the interface, as well as interface interatomic potentials. Calculations are performed for both coherent interfaces and semicoherent interfaces that approximate the lattic...