the aim of this work is to synthesize and investigate the performance of yttria-doped zirconia solgelcoatings in the chemical corrosion prevention of zircaloy-4 (zirconium alloy) in a 1 n h2so4environment. the influence of four different molar ratios of water to alkoxide, namely 1, 4, 12, and20, on the coating quality and its corrosion prevention performance was investigated. differentialtherma...

Sol-gel Ru(0.3)Sn(0.7)O(2) electrode coatings with crack-free and mud-crack surface morphology deposited onto a Ti-substrate are prepared for a comparative investigation of the microstructural effect on the electrochemical activity for Cl(2) production and the Cl(2) bubble evolution behaviour. For comparison, a state-of-the-art mud-crack commercial Ru(0.3)Ti(0.7)O(2) coating is used. The compac...

Sol–gel Ru0.3Sn0.7O2 electrode coatings with crack-free and mud-crack surface morphology deposited onto a Ti-substrate are prepared for a comparative investigation of the microstructural effect on the electrochemical activity for Cl2 production and the Cl2 bubble evolution behaviour. For comparison, a state-of-the-art mud-crack commercial Ru0.3Ti0.7O2 coating is used. The compact coating is pot...

This paper considers the explicit solutions of free-edge stresses near circumferential cracks in surface coatings of circular torsion bars and their application in determining the progressive cracking density in the coating layers. The problem was formulated within the framework of linear elastic fracture mechanics (LEFM). The free-edge stresses near crack tip and the shear stresses in the cros...

We report on the fabrication and characterization of thick UV-patternable hybrid sol-gel films by spin coating using a modified sol-gel process. Thick coating of 25 microns with crack-free surface can be produced by one spin coating step. Thick layers of more than 100 μm can be obtained with a multi-coating process. Characterization using different techniques including optical microscope and at...

A protocol is described to assess self-healing of crack damage in a polymer coating deposited on a substrate containing a microvascular network. The bio-inspired coating/substrate design delivers healing agent to cracks in the coating via a three-dimensional microvascular network embedded in the substrate. Through capillary action, monomer flows from the network channels into the crack plane wh...

A combined experimental/analytical work is carried out to elucidate the fracture resistance of a thin, hard coating bonded to a semi-infinite substrate due to indentation by a cylindrical surface. The bending of the coating under the softer substrate induces concentrated tensile stress regions at the lower and upper surfaces of the coating, from which cracks may ensue. The evolution of such dam...

Multiple healing cycles of a single crack in a brittle polymer coating are achieved by microvascular delivery of a two-part, epoxy-based self-healing chemistry. Epoxy resin and amine-based curing agents are transported to the crack plane through two sets of independent vascular networks embedded within a ductile polymer substrate beneath the coating. The two reactive components remain isolated ...

The role of elastic mismatch in determining critical conditions for indentation fracture in brittle coatings on substrates of unlike modulus was investigated. A model transparent trilayer system, consisting of a glass coating layer bonded to a thick substrate of different glass or polymer by a thin layer of epoxy adhesive, facilitated in situ observations of crack initiation and propagation. A ...