The complexation reaction between iodine and 1,10-Diaza-18-Crown-6 (DA18C6) has been studied in acetonitrile by spectrophotometric, biamperometric and conductometric techniques. The results are indicative of the formation of [(CH3CH)nI+.I¯3] from iodine and acetonitrile, and the formation of DA18C6 I+. I¯ from DA18C6 and [(CH...

An in-depth study of the ion transfer facilitated by complexation in the organic phase (TOC mechanism) in liquid membrane systems of one and two polarized interfaces is carried out by taking into account the kinetic effects associated with the complexation reaction. Explicit analytical equations for the normal pulse voltammetric (I/E) and chronoamperometric (I/t) responses with an explicit depe...

covalent grafting of mcm-41 with 3-chloropropyl trimethoxysilane and subsequent reaction respectively with acacdien and complexation with moo2(acac)2 afforded moo2acacdien@mcm-41. x-ray diffraction and nitrogen sorption analyses revealed the preservation of the textural properties of the support as well as accessibility of the channel system despite sequential reduction in surface area, pore vo...

the complexation reaction between 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane (kryptofix5) ligand with zn2+, ni2+, co2+, pb2+, mn2+ and cu2+ ions were studied conductometrically in different acetonitrile-nitromethane (an-nm) and acetonitrile-methanol (an-meoh) mixtures. the formation constants of the resulting 1:1 complexes were calculated from the computer fitting of the molar conductan...

Covalent grafting of MCM-41 with 3-chloropropyl trimethoxysilane and subsequent reaction respectively with acacdien and complexation with MoO2(acac)2 afforded MoO2acacdien@MCM-41. X-ray diffraction and nitrogen sorption analyses revealed the preservation of the textural properties of the support as well as accessibility of the channel system despite sequential reduction in surface area, pore vo...

a spectrophotometric method for selective complexation reaction and simultaneous determination of mycophenolate mofetil (mpm), and mycophenolic acid (mpa) using three multivariate chemometric methods, i.e. partial least squares regression, principal component regression and principal component artificial neural networks, is proposed. the method is based on the complexation reaction of mpm and m...

the complexation reaction between hydroxyl ammonium (honh3+ ) cation with 18-crown-6 (18c6) ligand was studied in dimethylsulfoxide – water (dmso-h2o), methanol – water (meoh-h2o) and dimethylformamid – methanol (dmf-meoh), binary solutions at different temperatures using conductometric method. the obtained results show that the stoichiometry of the complex formed between honh3+ cation with (18...

The sorption of copper ions onto natural bamboo sawdust with cellulose-lignin polymeric structure strongly depends on pH. The adsorption capacity for copper ions increases as increasing pH and copper loadings. The fitting of copper pH boundary curve by NEM surface complexation models shows that: three-sites model including the ion exchange reaction of permanent charge fits better than two-sites...

Two BTP-type N-donor ligands with different numbers of aromatic nitrogen atoms (2,6-bis(4-ethyl-pyridazin-1-yl)pyridine, Et-BDP and 2,6-bis(4-(n)propyl-2,3,5,6-tetrazine-1-yl)pyridine, (n)Pr-Tetrazine) have been synthesized and characterized by NMR and MS techniques. The complexation with Cm(III) in 2-propanol-water (1 : 1, vol.) is studied for both ligands using time resolved laser-induced flu...