The thermal valorization of glycerol to produce synthesis gas has been investigated under conventional and microwave heating systems. Different processes (pyrolysis, steam reforming and dry reforming) are compared, using a commercial activated carbon as catalyst. The reforming processes that employ oxidizing agents (CO2 or H2O) were found to promote higher glycerol conversions than mere termal ...

In this study we developed LaNixAl1-xO3 perovskite systems using a sol-gelmethod (with propionic acid as solvent) to use in methane-reforming reactions for producing synthesis gas. To understand the roles of the nature of the precursor and calcination conditions on the formation of LaNixAl1-xO3, we carried out identifications using NMR, FT-IR, XRD, SEM, and TEM. The precursor struc...

This paper focuses on the comparison of different glycerol reforming technologies aimed to hydrogen and syngas production. The reactions of steam reforming, partial oxidation, autothermal reforming, dry reforming and supercritical water gasification were analyzed. For this, the Gibbs energy minimization approach was used in combination with the virial Equation of state. The validation of the mo...

Environmental considerations will probably change automobile fuels from gasoline and gas-oil to hydrogen (as fuel cell) in the future. Problems of fossil fuels include producing gaseous pollutants, such as NOx, CO, and even SO2 (from incomplete-hydrotreated fuels), which need catalytic converters and greenhouse gas emission (such as CO2, CH4, N2O) from the exhaust with a drastic effect on globa...

In this work, an experimental study of biomass gasification in different operation conditions has been carried out in an updraft gasifier combined with a porous ceramic reformer. The effects of gasifier temperature, steam to biomass ratio (S/B), and reforming temperature on the gas characteristic parameters were investigated with and without porous ceramic filled in reformer. The results indica...

Abstract A series of supported Ni-Mo catalysts were synthesised through a deposition-co-precipitation method (DcP) and investigated in combined steam dry reforming. The prepared by Yttria-Stabilised Zirconia (YSZ), Gadolinium-Doped Ceria (GDC) Stabilised (CSZ) with improved carbon tolerance have the potential to be used as anodes Solid Oxide Fuel Cells (SOFC). These will applied anode supportin...

Several mesoporous nickel-based catalysts with MgO-Al2O3 as the catalyst support were prepared using a co-precipitation method at a constant pH. The supports were prepared from the decomposition of an Mg-Al hydrotalcite-like structure which had already been prepared with Mg/Al=1. Prior to impregnating 10 wt.% nickel on the supports, the precursor was decomposed at several ...

This work describes two different configurations of syngas production processes using a combination of steam methane reforming (SMR) and dry reforming of methane (DRM). The ideal SMR+DRM process ensures the maximum product yield, the heat-integrated SMR+DRM process fulfills the maximum heat recovery, and the stand-alone SMR+DRM process effectively suppress net CO2 emissions. Through kinetic mod...

The combined dry-steam reforming (CDSR) of a model biogas (66 % CH4 + 34 CO2) has been investigated under various feed compositions and reaction temperature conditions over Ni-Rh/MgAl2O4 catalyst, with the objective to convert excess methane (compared by steam (SR). Methane, however, appeared react preferentially H2O rather than CO2, leading an inhibition dry (DR) in presence steam. CO2 adsorpt...