In this study, mononuclear octahedral cobalt(III) Schiff base complex [CoL3], L = (5-bromo-2-hydroxybenzyl-2-furylmethyl)imine, was synthesized from the reaction of Co(NO3)2•6H2O and the Schiff base ligand L in methanol as solvent. It used as a new precursor to prepare spinel type cobalt oxide nanoparticles by a facile solid-state thermal decomposition. Controlling the temperature and time, Co3...

In this paper, single crystalline octahedral Co3O4 with dimensions about 100–500 nm and smooth surface has been prepared by solid-state thermal decomposition of cobalt(II) Schiff base complex Co((3,4-MeO-ba)2 en)Cl2 as new precursor at 450ºC under air atmosphere for 3.5 h. Surface morphology of the products were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray powder ...

In the title compound, [Co(NCS)(2)(C(11)H(13)NO(2))(2)], a mononuclear Schiff base cobalt(II) complex, the Co atom is six-coordinated by four O atoms from two Schiff base ligands, and by two N atoms from two thio-cyanate ligands, forming a distorted octa-hedral geometry. The central Co atom lies on a twofold rotation axis. An intramolecular N-H⋯O hydrogen bond is present.

A cobalt aquo-hydroxo complex of a ditopic Schiff-base pyrrole-crown ether macrocycle has been prepared and forms a rigid Pacman-clefted structure that assembles through hydrogen-bonding into a hexagonal wheel motif in the solid state.

The mixed Co(II)/Ni(II) complex, [Co2.67Ni1.33L₄(CH₃COO)₂][BPh₄]₂·0.75H₂O where HL = 4-(salicylaldimine)antipyrine, was isolated as an orange solid from the reaction of 4-(salicylaldimine)antipyrine, with mixed cobalt(II) acetate and nickel(II) acetate in ethanol. The complex was characterized by Frustrated Total Internal Reflection (FTIR), UltraViolet Visible spectroscopy (UV-Vis), X-ray singl...

The copper-catalyzed [3+2] azide-alkyne cycloaddition and the Staudinger ligation are readily applicable and highly efficient for the immobilization of cobalt Schiff base complexes onto polystyrene resins. Stepwise synthesis of polymer-bound Schiff bases followed by their subsequent complexation with metal ions were successfully carried out. Direct covalent attachment of preformed homogeneous c...

The Carboxymethyl chitosan Schiff base (CSB) derivative and its cobalt and nickel complexes (CSB-Co & CSB-Ni) have synthesized. The FTIR results showed the interaction with the amine of Carboxymethyl chitosan and aldehyde confirming the Schiff base formation. The XRD results, in comparison to CMC, displayed weaker peaks, which shows a decrease in crystalline properties and also exhibits the amo...