To investigate the preservation of CO2 clathrate hydrate in the presence of sugar for the novel frozen dessert, mass fractions of CO2 clathrate hydrate in CO2 clathrate hydrate samples coexisting with trehalose were intermittently measured. The samples were prepared from trehalose aqueous solution with trehalose mass fractions of 0.05 and 0.10 at 3.0 MPa and 276.2 K. The samples having particle...

Clathrate hydrates are inclusion compounds in which guest molecules are trapped in a host lattice formed by water molecules. They are considered an interesting option for future energy supply and storage technologies. In the current paper, time lapse 3D micro computed tomographic (µCT) imaging with ice and tetrahydrofuran (THF) clathrate hydrate particles is carried out in conjunction with an a...

Clathrate hydrates form the basis of a general model of biomolecule hydration. In clathrate hydrate crystal structures, the size of hydrogen-bonded water rings is highly constrained to five members. The clathrate hydrate model predicts that the size of water rings near biomolecule surfaces is similarly constrained to five members. This report describes a test of this model of biomolecule hydrat...

Clathrate hydrates are solid crystalline structures most commonly formed from solutions that have nucleated to form a mixed solid composed of water and gas. Understanding the mechanism of clathrate hydrate nucleation is essential to grasp the fundamental chemistry of these complex structures and their applications. Molecular dynamics (MD) simulation is an ideal method to study nucleation at the...

The thermodynamic stability of clathrate hydrate is calculated under a wide range of temperature and pressure conditions applicable to solar system problems, using a statistical mechanical theory developed by van der Waals and Platteeuw (1959) and existing experimental data on properties of clathrate hydrates and their components. At low pressure, dissociation pressures and partition functions ...

A new predictive computational method for classifying clathrate hydrate promoter molecules is presented, based on the interaction energies between potential promoters and the water networks of sII and sH clathrates. The motivation for this work is identifying promoters for storing hydrogen compactly in clathrate hydrates. As a first step towards achieving this goal, we have developed a general ...

Clathrate hydrates are crystalline compounds composed of hydrogen-bonded water molecules that form polyhedral cavities and trap small guest molecules such as methane, carbon dioxide, cyclopentane (CP), and tetrahydrofuran (THF). Understanding the formation and dissociation of clathrate hydrates is of significant importance to addressing some global challenges such as greenhouse gas mitigation a...

We report the first UV-vis spectroscopic study of bromine molecules confined in clathrate hydrate cages. Bromine in its natural hydrate occupies 51262 and 51263 lattice cavities. Bromine also can be encapsulated into the larger 51264 cages of a type II hydrate formed mainly from tetrahydrofuran or dichloromethane and water. The visible spectra of the enclathrated halogen molecule retain the spe...

Recently, for the first time a hydrate clathrate was discovered with hydrogen. Aside from the great technological promise that is inherent in storing hydrogen at high density at modest pressures, there is great scientific interest as this would constitute the first hydrate clathrate with multiple guest molecules per cage. The multiple cage occupancy is controversial, and reproducibility of the ...

The stability of hydrate frameworks is influenced by guest molecules capable of hydrogen bonding with surrounding water molecules. Four remarkable features from the ammonium fluoride incorporation into a crystalline hydrate matrix provide important information on the thermodynamic stability, formation kinetics, structural characteristics, and molecular behavior in clathrate hydrate systems.