the purpose of this investigation was directed to propose sensitive, accurate and reproducible methods of analysis that can be applied to determine distigmine bromide (dtb), cyclopentolate hydrochloride (cphc), diaveridine hydrochloride (dvhc) and tetrahydrozoline hydrochloride (thhc) drugs in pure form and pharmaceutical preparations via charge-transfer complex formation with 7,7,8,8-tetracyan...

the interaction between benzo-15-crown-5 (b15c5), dibenzo-18-crown-6 (db18c6), dibenzyl-daza-18crown-6 (dbzda18c6), n-phenyl-aza-15-crown-5 (npha15c5) and dibenzopyridine-18-crown-6 (dbpy18c6) with π-acceptor 2,3-dichloro-5,6-dicyanobenzoquinone (ddq) in chloroform solution was studied spectrophotometrically. the interaction of b15c5-ddq and db18c6-ddq caused the formation of 1:1 charge transfe...

the storage capacity of hydrogen on na-decorated born nitride nanotubes (bnnts) is investigated by using density functional theory within quantum espresso and gaussian 09. the results obtained predict that a single na atom tends to occupy above the central region of the hexagonal rings in (5,0) and (3,3) bnnt structures with a binding energy of -2.67 and -4.28 ev/na-atom respectively. when a si...

the complex formed as a consequence of the interaction between the electron-acceptor p-chloranilic acid and an electron donor tamoxifen citrate was employed in the assay of the drug in pure powder and tablets. chloranilic acid was found to form a charge-transfer complex in a 1:1 stoichiometric ratio, with tamoxifen citrate. the wavelength of maximum absorption for the complex was found to be 55...

the complex formation reaction between iodine with tetrabutylammonium halides (tbax) has been studied spectrophotometrically in chloroform solution at 25ºc. various aspects of the spectra of iodine in the presence of various concentration of different tetrabutylammonium halides have been discussed in terms of electronic specifications of iodine and halides. in the case of tetrabutylammonium iod...

In the present work, the sensitivity to the moisture (hygroscopisity) is studied for 3,4-dinitropyrazole (DNP) as a famous energetic molecule. All of the DNP-H2O complex systems (1-3) as well as individual molecules were optimized and bond lengths, bond angles, dihedral angles, charge transfer and stability via NBO analysis, corrected interaction energies with ZPE + BSSE and hydrogen bonds anal...

[ru(terpy)(bpy)(l)]pf6 complexes, where terpy is 2,2΄:6′,2″– terpyridine, bpy is 2,2΄ - bipyridine and l is monoanions of  4 - bromophenylcyanamide (4 - brpcyd), 4-methoxyphenylcyanamide (4 - meopcyd), 2, 4 - dibromophenylcyanamide (2,4 - br2pcyd), 2,4-dimethylphenylcyanamide (2,4 - me2pcyd), 2 - methylphenylcyanamide  (2 - mepcyd), phenylcyanamide  (pcyd) and naphtylcyanamide  (ncyd)  have bee...