Open-framework chalcogenides are potential electrode materials for sodium-ion batteries (SIBs) due to their architectures with fast-ion conductivity. Herein, we report on the successful synthesis of open-framework Cu-Ge-based chalcogenides [Cu8Ge6Se19](C5H12N)6 (CGSe) and the research of their energy storage application as SIB anodes for the first time. As a result, the CGSe anode exhibited goo...

The numerical analysis of electrical properties involved in transport mechanism such as carrier concentration, carrier mobility, carrier effective mass, electrical resistivity and electrical conductivity for some rare earth chalcogenides is discussed. The formulae are derived and used to obtain numerical values of these electrical parameters, which are useful to describe the electrical behavior...

This is a review of the magnetism and superconductivity in '11'-type Fe chalcogenides, as compared to the Fe-pnictide materials. The chalcogenides show many differences from the pnictides, as might be anticipated from their very varied chemistries. These differences include stronger renormalizations that might imply stronger correlation effects as well as different magnetic ordering patterns. N...

Sulfides are promising candidates for environment-friendly and cost-effective thermoelectric materials. In this article, we review the recent progress in all-length-scale hierarchical architecturing for sulfides and chalcogenides, highlighting the key strategies used to enhance their thermoelectric performance. We primarily focus on TiS₂-based layered sulfides, misfit layered sulfides, homologo...

Transition metal chalcogenides are an important family of materials that have received significant interest in recent years as they have the potential for diverse applications ranging from use in electronics to industrial lubricants. One of their most exciting properties is the ability to generate electricity from incident light. In this perspective we will summarise and highlight the key resul...

The efficient and mild copper-catalyzed synthesis of unsymmetrical diorganyl chalcogenides under ligand- and solvent-free conditions is described. The cross-coupling reaction was performed using aryl boric acids and 0.5 equiv. of diorganyl dichalcogenides (Te/Se/S) in the presence of 3 mol % of CuI and 3 equiv. of DMSO, under microwave irradiation. This new protocol allowed the preparation of s...

Owing to their strong photon emission, low excitonic binding energies, and nearly-ideal band offset values for water splitting reactions, direct gap quasi-2D gallium chalcogenides are potential candidates for applications in energy harvesting, optoelectronics, and photonics. Unlike other 2D materials systems, chemical functionalization of gallium chalcogenides is still at its seminal stages. He...

We are facing a new paradigm in superconductivity research with the discovery of superconductivity in iron pnictides (LaFeAsO, SrFe2As2, BaFe2As2, etc.) and the iron chalcogenides (FeTe and FeSe). Both classes of ironbased materials, for some as yet unknown reason, have proven to be fertile ground for novel superconductivity, with the transition temperature of the pnictides racing above 50 K. A...

Open framework metal chalcogenides are a family of porous semiconducting materials with diverse chemical compositions. Here we show that these materials containing covalent three-dimensional superlattices of nanosized supertetrahedral clusters can function as efficient photocatalysts for the reduction of CO2 to CH4. Unlike dense semiconductors, metal cations are successfully incorporated into t...