On the basis of Maxwell's equations and a plane wave expansion method, photonic band structure is computed for 3D chalcogenide photonic crystal with diamond lattice. The geometrical influence on the photonic bandgap is studied for three dimensional chalcogenide photonic crystal of diamond lattice for both chalcogenide spheres in air and air spheres in chalcogenide background. The air spheres in...

One-dimensional metal chalcogenide nanostructures are important candidates for many technological applications such as photovoltaic and thermoelectric devices. However, the design and synthesis of one-dimensional metal chalcogenide nanostructured materials with controllable components and properties remain a challenge. We report a general chemical transformation process for the synthesis of mor...

Metal chalcogenide semiconductor nanocrystals (NCs) are ideal inorganic materials for solar cells and biomedical labeling. In consideration of the hazard and instability of alkylphosphines, the phosphine-free synthetic route has become one of the most important trends in synthesizing selenide QDs. Here we report a novel phase transfer strategy to prepare phosphine-free chalcogenide precursors. ...

*Correspondence: Vladimir S. Shiryaev , G.G. Devyatykh Institute of Chemistry of High-Purity Substances of the Russian Academy of Sciences, 49 Tropinin Street, Nizhny Novgorod 603950, Russia e-mail: [email protected] The recent developments on chalcogenide glass hollow-core microstructured optical fibers (HC-MOFs) are presented. The comparative analysis of simulated optical properties for c...

We report the first demonstration of error-free 640 Gbit/s demultiplexing using the Kerr non-linearity of an only 5 cm long chalcogenide glass waveguide chip. Our approach exploits four-wave mixing by the instantaneous nonlinear response of chalcogenide. Excellent performance is achieved with only 2 dB average power penalty and no indication of error-floor. Characterisation of the FWM efficienc...

We computationally study fiber loss in negative curvature fibers made with silica, As2S3 chalcogenide, and As2Se3 chalcogenide glasses with a fixed core-diameter-to-wavelength ratio of 30. We consider both simple and nested geometries as the transmission wavelength varies. At wavelengths shorter than 4.5 μm, silica negative curvature fibers have a loss that is around or below 10–1 dB/m and are ...

We demonstrate low Raman-noise correlated photon-pair generation in a dispersion-engineered 10 mm As2S3 chalcogenide waveguide at room temperature. We show a coincidence-to-accidental ratio (CAR) of 16.8, a 250 times increase compared with previously published results in a chalcogenide waveguide, with a corresponding brightness of 3×10(5) pairs·s(-1)·nm(-1) generated at the chip. Dispersion eng...

Chalcogenide glasses, with high nonlinearity and low loss, have captured research interest as an integrated device platform for near- and mid-infrared nonlinear optical devices. Compared to silicon-based microfabrication technologies, chalcogenide fabrication processes are less mature and a major challenge is obtaining high quality devices. In this paper, we report a hybrid resonator design lev...

In the absence of suitable deposition processes, the fabrication of graded-index chalcogenide waveguides or fibers remains an outstanding challenge. Here, by exploiting the strong thermo-optic effect present in chalcogenide glasses, we experimentally demonstrate non-permanent optically-induced waveguides in bulk As2Se3 rods using a 1.55 μm wavelength laser. This single-ste...