Cerussite, an orthorhombic lead carbonate mineral, has a structure and physical properties that cannot be understood merely in terms of ionic anion-cation interactions. The nature of the chemical bonding in cerussite is analyzed by means of the quantum theory of atoms in molecules (QTAIM) and the analysis of the electron localization function (ELF). A long C-C attractive interaction (3.077 Å) a...

Chloride ions were found to potentially increase activity of cerussite surfaces. Dissolution experiments, zeta potential measurements, X-ray photoelectron spectroscopy (XPS) studies, and density functional theory (DFT) computation were conducted in this study. Dissolution experiments showed that the lead ion concentrations in the NaCl solution system were lower than those in the deionized water...

The processing mineralogy characteristics of an oxidized lead-zinc ore from Sichuan were studied systematically using numerous modern instruments. Results showed that lead and zinc oxide content in the ore exceeded the minimum industrial grade, and also included a relatively high concentration of silver and iron. This ore is composed of many different minerals. Major zinc-containing minerals in...

A case study of cerussite-dominated mine tailings (5-7 wt% Pb) from the former lead-zinc Grogwynion Mine, Mid Wales (UK), is presented with the objective of providing an improved understanding of the chemical speciation that controls element release from the waste in the short and long term. An experimental and modelling approach was used to examine the effects of pH changes in fresh waters int...

The O/O and C/C ratios of carbonate minerals formed by supergene oxidation of Zn–Pb deposits and submarine alteration of ancient slags were studied in order to constrain isotope fractionation factors for smithsonite, cerussite, and phosgenite, and to characterize conditions of nonsulfide ore formation. We present new isotope data of carbonate-hosted ores from the Iglesiente district (Sardinia, ...

Sulfide lead resources are being depleted and the exploitation of carbonate lead deposits is now the main focus of lead mining. Cerussite, PbCO3, is majorly discarded to tailing damps because it is difficult to be processed by flotation in lead concentration units. This paper not only investigates the optimization of cerussite flotation, but it also proposes a model for predict...

Elemental lead is a known toxic metal that can pose threats to human health and can be found in a variety of sources including drinking water at very low level concentrations (i.e. μg/L range). Destabilization of the corrosion scale at the inner layer of pipeline is the major source of lead in drinking water. Chemical properties of the water passing through the distribution system such as pH, a...