In this paper, conventional SAPO-34 and Cerium Hierarchical SAPO-34 zeolites are synthesized using a hydrothermal method for methanol-to-propylene (MTP) reaction. The Ce-H-SAPO-34 catalyst shows a slightly larger crystal size, bimodal pore size distribution (microporous and mesoporous) and lower surface acidity compared to conventional SAPO-34 catalysts. According to these physicochemical prope...

A series of H-SAPO-34 zeolites were synthesized by a hydrothermal method in fluoride media. The as-synthesized H-SAPO-34 zeolites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), N2 physisorption, temperature-programmed desorption of NH3 (NH3-TPD) and nuclear magnetic resonance (NMR) measurements. The results showed that a certain concentration of F(-) anions p...

This study focuses on co-cations modified copper based molecular sieve catalyst CuCe/SAPO-34. The SCR performance and low temperature hydrothermal stability of Cu/SAPO-34 CuCe/SAPO-34 before after 70 ? aging were evaluated to conclude the impact Ce structure mechanism NH3-SCR reaction. For fresh samples, showed higher catalytic activity at whole range, especially below 250 above 400 in comparis...

Molecular sieve catalysts containing transition metals have been attracting attention for their potential applications in various fields, including environmental and industrial catalysis. A Cu-Ce-Zr/SAPO-34 series of molecular were prepared by the impregnation method, effect Zr introduction on selective catalytic reduction NO Cu-Ce/SAPO-34 was explored. Through characterization methods, physica...

The product distribution of methanol to hydrocarbons conversion over SAPO-34 and ZSM-5 catalysts was studied using thermodynamic equilibrium and Anderson-Schulz-Flory (ASF) distributions. The equilibrium compositions were calculated using constrained Gibbs free energy minimization. The effect of catalyst type was considered by setting upper limits to product carbon number due to sh...

In order to enhance the catalytic performance of SAPO-34 catalyst for the reaction of methanol to olefins (MTO), ultrasonic and microwave-assisted aging method were employed in static hydrothermal method to synthesize nano-sized SAPO-34. The effects of the application of this method on the chemical composition, morphology, surface area and total acidity of SAPO-34 were characterized by XRD, FE-...

The generation of hexamethylbenzenium radical cations as the key reaction intermediate in chabazite-type molecular sieve acids (i.e., H-SAPO-34 and H-SSZ-13) during the methanol-to-olefin process has been directly evidenced by ESR spectroscopy.

•Cr2O3(SG)/H-SAPO-34 shows a C2=?C4= selectivity of 95.7% in CO2 hydrogenation •Ethene accounts for more than 74% light olefins with an E/P ratio reaching 3.1 •Ethanol is formed through the reaction H3CO? and H? on Cr2O3(SG) converted into ethene SAPO-34 leads to high Conversion effective strategy sustainable utilization fossil energy biomass. However, highly selective production specific olefi...