a catalytic-kinetic method for the determination of selenium is proposed. alizarin navy blue is reduced by sodium sulfide to from a colorless product. the reaction is accelerated by trace amounts of se (iv), and can be followed by measuring the decrease in absorbance of the dye at 620nm and 30 °c by the fixed time method. selenium can be determined in the range of 0.004 — 0.12 1.1g.m1-1 . ...

kinetic monte carlo simulation was applied to investigation of kinetics and mechanism of oxalic acid degradation by direct and heterogeneous catalytic ozonation. la-containing perovskites including lafeo3, lanio3, lacoo3 and lamno3 was studied as catalyst for oxalic acid ozonation. the reaction kinetic mechanisms of each abovementioned catalytic systems has been achieved. the rate constants val...

Cocaine is one of the most addictive drugs, and there is still no FDA (Food and Drug Administration)-approved medication specific for cocaine abuse. A promising therapeutic strategy is to accelerate cocaine metabolism, producing biologically inactive metabolites via a route similar to the primary cocaine-metabolizing pathway, i.e. cocaine hydrolysis catalyzed by butyrylcholinesterase (BChE) in ...

mercaptans are commonly present in petroleum products. their foul odor and highly corrosive nature make them the most undesirable sulfur compounds so they should be removed because of environmental issues. merox process is used for oxidation of mercaptans to disulfide using air in the presence of alkaline solution and merox catalyst. in this paper, due to lack of information about the kinetic o...

Kinetic Monte Carlo simulation was applied to investigation of kinetics and mechanism of oxalic acid degradation by direct and heterogeneous catalytic ozonation. La-containing perovskites including LaFeO3, LaNiO3, LaCoO3 and LaMnO3 was studied as catalyst for oxalic acid ozonation. The reaction kinetic mechanisms of each abovementioned catalytic systems has been achieved. The rate constants val...

Recent studies of the hairpin ribozyme have revealed a distinct catalytic mechanism for this small RNA motif. Inner-sphere coordinated metal ions are not required, as the inert metal ion complex cobalt hexammine promotes catalysis. Detailed kinetic analyses have defined rates of individual steps in the catalytic cycle. Functional group modification, NMR studies of subdomains and cross-linking e...

The kinetics of the liquid-phase alkylation guaiacol (G) with cyclohexene (CH) over Amberlyst 36 resin was studied using Langmuir–Hinshelwood–Hougen–Watson (LHHW) heterogeneous kinetic models. Catalytic tests were performed in a batch reactor, solvent-less conditions, at 363 K, 1 bar, 600 RPM, G:CH molar ratio equal to 5 total volume 30 ml and 1.5 g solid catalyst. G CH formed cyclohexyl-2-meth...