a new carboxylic acid extractant, named 2-(dibutylcarbamoyl)benzoic acid, is prepared and its potential for selective solvent extraction and recovery of lead ions from industrial samples was investigated. the slope analysis indicated that the lead ions are extracted by formation of 1:2 metal to ligand complexes. the effect of the parameters influencing the extraction efficiency including kind o...

Nicotinic acid (also known as pyridine-3-carboxylic acid) is widely used in food, pharmaceutical and biochemical industries. The extraction of nicotinic acid by tri-noctylphosphine oxide (TOPO) with kerosene (diluent) is studied. The equilibrium experiments are carried out to investigate the effects of diluent, extractant (TOPO) composition and initial acid concentration on extraction efficienc...

A new carboxylic acid extractant, named 2-(dibutylcarbamoyl)benzoic acid, is prepared and its potential for selective solvent extraction and recovery of lead ions from industrial samples was investigated. The slope analysis indicated that the lead ions are extracted by formation of 1:2 metal to ligand complexes. The effect of the parameters influencing the extraction efficiency including kind o...

The separation (or removal) of organic residues from aqueous waste streams released from industries is important and essential from the points of view of pollution control and recovery of useful materials. The disposal of waste waters containing most widely-used industrial organic acids such as acetic acid, formic acid and propionic acid has been recognized as a significant expense to the indus...

Propionic acid is a carboxylic acid produced by fermentation and widely used in chemical, pharmaceutical and food industries. It is used primarily for animal feed preservation, including hay, silage, and grains, and in human foods (mainly in baked goods and cheeses). The growing demand of this acid draws attention towards a more economical energy efficient technology. The conventional methods f...

Nicotinic acid is widely used in the food, pharmaceutical and biochemical industries. Fermentation technology for the production of nicotinic acid in particular has been known for more than a century and acid have been produced in aqueous solutions. Reactive liquid-liquid extraction for the recovery of the organic acids by a suitable extractant has been found to be a promising alternative to th...

This paper deals with propionic acid extraction by Aliquat 336, a quaternary amine dissolved in ndodecane and 1-decanol. Chemical equilibrium experiments have been carried out to investigate the effect of modifier, 1-decanol on the extraction efficiency of Aliquat 336 in ndodecane at fixed initial acid concentration of 0.27 gmol/l. Extraction efficiency is determined in terms of distribution co...

The chemical degradation of an extraction solvent composed of a mixture of tri-n-octylamine (extractant) and 1-tridecanol (phase modifier) in n-dodecane in contact with an acidic aqueous sulfate solution containing chromium(VI) has been investigated. The kinetics of degradation and the degradation products have been determined. GC-MS analyses evidenced the formation of 1-tridecanal, di-n-octyla...

the feasibility of extractive reaction of methacrylic acid from aqueous solution using a quaternary amine, tri–octyl methyl ammonium chloride (tomac) as an extractant, was studied. the diluents chosen in the present work belong to different chemical classes, n–butyl acetate, carbon tetrachloride, isoamyl alcohol, methyl isobutyl ketone, and toluene. the effect of initial acid concentration in t...