Experiments were conducted to determine CO2 solubilities in alkali basalts from Vesuvius, Etna and Stromboli. The basaltic melts were equilibrated with nearly pure CO2 at 1200°C under oxidizing conditions, and at pressures ranging from 269 to 2060 bars. CO2 solubility was determined by FTIR measurements. The results show that alkalis have a strong effect on the CO2 solubility and confirm and re...

Prediction of solubility in SuperCritical CO2 (SC-CO2) as a function of system pressure (P) and temperature (T) aids selection of process condition for extraction processes. Several equations have being used to correlate solubility as a function of P and T, but best-fitting procedures typically demand a large set of experiments. Previously, other groups have developed semi-empirical models to p...

the solubility of co2 in the primary, secondary, tertiary and sterically hindered amine aqueous solutions at various conditions was studied. in the present work, the modified kent-eisenberg (m-ke), the extended debye-hückel (e-dh) and the pitzer models were employed to study the solubility of co2 in amine aqueous solutions. two explicit equations are presented to evaluate the concentration of h...

CO2 is the main greenhouse gas which causes global climatic changes on larger scale. Many techniques have been utilised to capture CO2. Membrane gas separation is a fast growing CO2 capture technique, particularly gas separation by composite membranes. The separation of CO2 by a membrane is not just a process to physically sieve out of CO2 through the controlled membrane pore size. It mainly de...

This paper discusses the application of the dynamic method to measure the solubility in pseudo-ternary systems formed by vegetable raw materials (cellulosic structure+solute) and CO2. For aromatic, medicinal, and spice plants, the soluble portion of the solid is formed of essential oils, oleoresins, pigments, and various substances from several other classes of organic compounds. The experiment...

alkanolamine solutions such as 2-amino-2-methyl-1-propanol (amp) are widely used in chemical industries for the removal of acid gases such as co2 and h2s. in this work, the density of co2, amp, water, and amp solutions using the goharshadi–morsali–abbaspour equation of state “gma eos” in the extended 50-degree range of temperatures (313.06-362.65 k) and pressures (0.5-40 mpa) was calculated. th...

solubility of high molecular weight n-paraffins in supercritical carbon dioxide has been a matter of interest to many researchers. however, not sufficient solubility experimental data are available although the methods by which the experimental data are obtained have many varieties. utilizing cubic equations of state is an effective method for solubility prediction of n-paraffins in supercritic...

Ionic liquids have been objects of extensive research for physical sorption of CO2 and a number of myths have been perpetuated in the literature, for lack of a critical analysis, concerning their potential for CO2 capture. This study carries a critical analysis of a number of widely accepted ideas and others not so well accepted that have been repeatedly expressed in the literature concerning t...

In this study, the solubility of CO2 in DEA in the presence and absence of choline chloride was reported at different temperatures of 276.15, 298.15, 313.15, and 333.15 K, and pressure range of 4-15 bar. The solubility of CO2 was evaluated using the pressure decay method in a batch isochoric stirred absorption cell. Also, the design of experiments performed with Qualitek-4 software using the Ta...

maceutical industry for production of fine drug particles with narrow size distribution, separation of active ingredients and preparation of microemulsions and sustained drug delivery systems. Supercritical carbon dioxide (SC-CO2) is a very popular fluid for pharmaceutical applications, as it is nontoxic, non-flammable and of low cost. Furthermore, because of its low critical temperature and pr...