نتایج جستجو برای: C-H…π interaction
تعداد نتایج: 1563823 فیلتر نتایج به سال:
We construct the complete SU(2) parity-violating (PV) π,N,∆ interaction Lagrangian with one derivative, and calculate the chiral corrections to the PV Yukawa NNπ coupling constant hπ through O(1/Λχ) in the leading order of heavy baryon expansion. We discuss the relationship between the renormalized hπ, the measured value of hπ, and the corresponding quantity calculated microscopically from the ...
We introduce the notion of rational Hopf algebras that we think are able to describe the superselection symmetries of two dimensional rational quantum field theories. As an example we show that a six dimensional rational Hopf algebra H can reproduce the fusion rules, the conformal weights, the quantum dimensions and the representation of the modular group of the chiral Ising model. H plays the ...
Two new strongly AEE active (I/I0 ≈ 94) tetraphenylsilole-containing cyclosiloxanes with cyan emissions (λem = 500 nm) and ∼100% solid state fluorescence quantum yields are reported. The intra- and intermolecular C-Hπ interactions in the crystal play a major role in the observed high solid state fluorescence quantum yields.
The synthesis of new Schiff base-like ligands with extended π-system and their iron complexes is described. Some of the iron(ii) complexes with N-heterocycles as axial ligands show spin crossover behaviour. The influence of the extended aromatic system on cooperative interactions is investigated by single crystal X-ray structure analysis, X-ray powder diffraction, and magnetic measurements. A c...
The purpose of this paper is to introduce and study the notion of a vector-valued π-invariant mean associated to a unitary representation π of a locally compact groupG on S, a self-adjoint linear subspace containing I of B(Hπ). We obtain, among other results, an extension theorem for π-invariant completely positive maps and π-invariant means which characterizes amenability of G. We also study v...
A bis-urea-functionalized pillar[5]arene has been synthesized and shown to form [2]pseudorotaxanes spontaneously with linear alkyl dicarboxylates in highly polar solvent DMSO, in which the hydrogen bonding interactions between the bis-urea hydrogens and dicarboxylate oxygens play an important role in stabilizing the novel [2]pseudorotaxanes alongside C-Hπ interactions.
A qualitative and quantitative energetic and structural study of dibenzyl ketone (DBK) and benzyl ethyl ketone (BEK) was carried out in order to obtain insights into the type and magnitude of aromatic interactions that these systems present in their different phases. The crystal structure of DBK was obtained by X-ray crystallography, and it shows that the conformation adopted in the crystalline...
From the recent measurement of parity nonconservation (PNC) in the Cs atom we have extracted the constant of the nuclear spin dependent electron-nucleon PNC interaction, κ = 0.44(7); the anapole moment constant, κa = 0.38(7); the strength of the PNC proton-nucleus potential, gp = 7 ± 1.4 (exp.) ± 1.5 (theor.); the π-meson-nucleon interaction constant, fπ ≡ hπ = [10 ± 2.5 (exp.) ± 3.5 (theor.)] ...
Let U(M) be the unitary group of a finite, injective von Neumann algebra M . We observe that any subrepresentation of a group representation into U(M) is amenable in the sense of Bekka; this yields short proofs of two known results—one by Robertson, one by Haagerup—concerning group representations into U(M). A unitary representation π of a group Γ on a Hilbert space Hπ is amenable if there exis...
A wavelet, in the generalized sense, is a vector in the Hilbert space, Hπ , of a unitary representation, π, of a locally compact group, G, with the property that the wavelet transform it defines is an isometry of Hπ into L2(G). We study the image of this transform and how that image varies as the wavelet varies. We obtain a version of the Peter-Weyl Theorem for the class of groups for which the...
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