An efficient synthesis of 2H-thiopyran derivatives via three-component reaction of alkyl propiolate, benzoyl isothiocyanate or its derivatives and alkyl bromides in the presence of triphenylphosphine in water at 80o C without using any catalyst in water is described. The method offers several advantages including high yields of products and an easy work-up procedure.

In this study new 2-(4-methyl-phenoxymethyl)benzoyl thioureas, N-[(R-amino)thioxomethyl]-2-[(4methylphenoxy)methyl]benzamides, were synthesized by the reaction of 2-(4-methyl-phenoxymethyl)benzoyl isothiocyanate with different amines. Structures of the new compounds were identified by spectroscopic technique and also confirmed by elemental analysis. The compounds will be screened for their in v...

A new ligand {N-[(benzoyl amino)-thioxo methyl] proline} was prepared by the reaction of benzoyl isothiocyanate with proline. The ligand was characterized by FTIR, UV-Visible, and 1 HNMR.Some complexes of the ligand were synthesized and characterized on the basis of their FTIR, UV-Visible spectroscopy, conductive measurements and magnetic susceptibility. From the results obtained, the following...

A novel method for oxazine derivatives formation is established using the reaction of ammonium thiocyanate and acid chlorides with 1-naphthol in the presence of Nanoparticle of ZnO to afford [1,3]oxazine-4-thione derivatives under solvent-free conditions at room temperature in excellent yields. 

Chitosan (1) was reacted with phenylisothiocyanate in 5% AcOH/H2O to give N-phenylthiocarbamoyl chitosan (2) with a degree of substitution (DS) of N-phenylthiocarbamoyl groups of 0.86 in 87.1% yield. The following acylation of compound 2 with hexanoyl chloride in the presence of pyridine afforded 3,6-di-O-2,3-hexanoyl chitosan isothiocyanate (4a) with a DS of the isothiocyanate groups of 0.70 i...

       Volatile constituents of the seed kernel and leaf of cultivated Moringa peregrina (Forssk.) Fiori, Agricolt collected after hydrolysis were analyzed by GC and GC/MS. Five glucosinolate degradation products which constituted almost the whole isolated oil of the seed kernel were identified to be: isobutyl isothiocyanate (94.0%), isopropyl isothiocyanate (4.9%), sec-butyl isothiocy...

volatile constituents of the seed kernel and leaf of cultivated moringa peregrina (forssk.) fiori, agricolt collected after hydrolysis were analyzed by gc and gc/ms. five glucosinolate degradation products which constituted almost the whole isolated oil of the seed kernel were identified to be: isobutyl isothiocyanate (94.0%), isopropyl isothiocyanate (4.9%), sec-butyl isothiocyanate (0.5%), n-...

Novel derivatives were prepared by reaction of aromatic amines with 2-(4-ethylphenoxymethyl)benzoyl isothiocyanate, affording the N-[2-(4-ethylphenoxymethyl) benzoyl]-Nꞌ-(substituted phenyl)thiourea. Structural elucidation of these compounds was performed by IR, NMR spectroscopy and elemental analysis. The new compounds were used in combination with Fe3O4 and polyvinylpyrrolidone (PVP) for the ...