Diazahexathia-24-crown-8 (2) has been isolated from the reaction mixture during the preparation of monoazatrithia-12-crown-4 (1). When N-Boc protected bis(2-chloroethyl)amine was employed as a starting material, N-Boc protected monoazatrithia-12-crown-4 (3) and N-Boc protected diazahexathia-24-crown-4 (4) were separated easily. Double-armed diazahexathia-24-crown-8 having two 3',5'-dichlorobenz...

New pyridylmethyl armed-monoazadithiaoxa- and monoazatrithia-12-crown-4 have been prepared. The structures of the Ag+ complexes of the new ligands were investigated by X-ray crystallography, 1H NMR titrations, and FAB-MS measurements. In all cases, the Ag+ complexes form dimetallo[3.3]para- or metacyclophane structures depending on the position of the N atom of the pyridine rings.

Let $G$ be a graph. Let $f:V(G)to{0,1,2, ldots, k-1}$ be a map where $k in mathbb{N}$ and $k>1$. For each edge $uv$, assign the label $left|f(u)-f(v)right|$. $f$ is called a $k$-total difference cordial labeling of $G$ if $left|t_{df}(i)-t_{df}(j)right|leq 1$, $i,j in {0,1,2, ldots, k-1}$ where $t_{df}(x)$ denotes the total number of vertices and the edges labeled with $x$.A graph with admits a...

The Scanian War fought between Sweden and Denmark (1675–1679) is an example of armed conflict, which uncovers the clash commercial political interests. This article analyses dispute allies, Danish Crown Dutch States General considering trade with Sweden. naval officials had captured confiscated cargoes seven tar vessels, heading to Amsterdam from present-day Finland in 1677, resulted a major Re...