Ultrasonic velocities in solution of tetrabutylammonium bromide (TBAB) in 10, 20 and 30 %w/w N, N– dimethylformamide (DMF)-water mixtures were measured at 303 K, 308 K and 313 K by using the pulse echo overlap method at a frequency of 3 MHz. The ultrasonic velocity, density, and viscosity were used to calculate the adiabatic compressibility, apparent molal compressibility, apparent molal volume...

The ultrasonic velocity (U), density ( ρ) and viscosity (η) measurements have been carried out for four amino acids namely L-alanine, L-leucine, L-valine and L-proline in aqueous sodium acetate solution as a function of composition at 303, 308 and 313K. Experimental data have been used to estimate the adiabatic compressibility (β), change in adiabatic compressibility (∆β), relative change in ad...

density (r/g cm-3) and viscosity (h/10-2gcm-1s-1=1centipoise,cp) of guanosine monophosphate (gmp) and adenosine triphosphate (atp) referred to as nucleotide, and 2-deoxy adenosine (doa) and thymidine (tmd) as nucleoside along with their integral furanose sugar, 2-deoxy ribose (dor) from 0.0004 to 0.0014mol kg-1 solution have been measured at 288.15, 293.15 and 298.15k at atmospheric pressure. t...

The present experimental investigation was carried out in order to explore the possible thermodynamic and interactions studies of D(+) fructose with mixed solvent of aqueous alkali metal halides at different molalities and constant temperature. Experimental values of densities and ultrasonic velocities were carried out of the ternary mixture solution D(+)fructose with aqueous NaCl ,KCl , MgCl2 ...

Acoustic properties like partial molal volume (φ) apparent molal Compressibility(φk(s)), adiabatic compressibility(βs), intermolecular freee path length (Lf), specific acoustic impendence (Z) and relative association(RA) have been evaluated by studying ultrasonic velocities and densities of dicarboxylic acid ltaconic acid. Malonic acid, Maleic acid and Succinic acid in different percentage of d...

Densities ρ and Viscosities ŋ of D-Galactose D-Maltose (0.05-0.4)M in aqueous solution (0.25) M Na2S at 298.15, 303.15 308.15K have been measured. From these experimental data, apparent molal Volume Limiting Apparent Molal ( ) ,The slope , Jones-Dole coefficient A B, The free energy activation viscous flow (ΔG*), enthalpies (ΔH*) Entropies (ΔS*) were calculated, values compatible with the weak ...

Densities and viscosities of L-Threonine in water mixed aqueous solution tetrahydrofurfurylalcohol at 298.15K. On the basis these data ,the apparent molal volumes ,partial infinite dilution °, slop ,transfer volume , Gibbs free energy activation for viscous flow ΔG*1,2 B-coefficient have been calculated using Jones-Dole equation . The obtained thermodynamic properties discussed terms intermolec...

The aqueous solution behavior of some rare-earth chlorides has been investigated at 25° C. in the concentration range between 0.02 molal and saturation. Density measurements on solutions of lanthanum, neodymium, samarium, gadolinium, dysprosium, erbium, and ytterbium chlorides were carried out by a pycnometric method with an estimated accuracy of 1 x 10-5 gm.per ml. From the density data the ap...

The ultrasonic velocity (U), density (ρ) and viscosity (η) measurements have been carried out for L-Methionine in aqueous sodium chloride, potassium chloride and lithium chloride as a function of composition at 303K. Experimental data have been used to estimate the adiabatic compressibility (β), change (∆β) and relative change in adiabatic compressibility (∆β/β°), acoustic impedance (z), limiti...