In this study, modeling of hydrogen, nitrogen, carbon monoxide, methane and carbon dioxide sorption on UTSA-16 framework extrudates in the pressure swing adsorption process was carried out. The pure gas adsorption of these gases at the pressure range (0 to 80) bars at (298, 313, and 338) K have also been measured in a fixed bed. Langmuir, Toth, Sips, UNILAN, Virial and Dubinin-Astakhov adsorpti...

nitrogen is produced mainly from its most abundant source, the air, using three processes: membrane, pressure swing adsorption (psa) and cryogenic. the most common method for evaluating a process is using the selection diagrams based on feasibility studies. since the selection diagrams are presented by different companies, they are biased, and provide unsimilar and even controversial results. i...

The new shaped structured adsorber, carbon monolithic adsorber, are characterized by straight parallel channels separated by thin wall, high void fraction and large geometric surface area, resulting in a low pressure drop under high flow rate and large contact area. These properties make it have the advantage on adsorption application. This study simulates the adsorption separation of 30% butan...

A commercial activated carbon supplied by Norit, R2030CO2, was evaluated as CO2 adsorbent under conditions relevant to post-combustion CO2 capture (ambient pressure and diluted CO2). It has been demonstrated that this carbon possesses sufficient CO2/N2 selectivity in order to efficiently separate a binary mixture composed of 17 % CO2 in N2. Moreover, this carbon was easily completely regenerate...

In this study pre-combustion capture of carbon dioxide from hydrogen was performed using a 5A zeolite adsorber. A one column thermal pressure swing adsorption (TPSA) process was studied in the bulk separation of a CO2/H2 mixture (50:50 vol%). The adsorption dynamics of the zeolite bed were investigated by breakthrough experiments to select the suitable range for operational factors in the desig...

Nitrogen gas is a staple of the chemical industry. Because it is an inert gas, nitrogen is suitable for a wide range of applications covering various aspects of chemical manufacturing, processing, handling, and shipping. Due to its low reactivity, nitrogen is an excellent blanketing and purging gas that can be used to protect valuable products from harmful contaminants. It also enables the safe...

Separation of olefin/paraffin is an energy-intensive and difficult separation process in petrochemical industry. Energy-efficient adsorption process is considered as a promising alternative to the traditional cryogenic distillation for separating olefin/paraffin mixtures. In this work, we explored the feasibility of adsorptive separation of olefin/paraffin mixtures using a magnesium-based metal...