نتایج جستجو برای: ARGET ATRP

تعداد نتایج: 692  

Journal: :Chemical communications 2011
Wei Ma Hideyuki Otsuka Atsushi Takahara

Poly(methyl methacrylate) grafted imogolite clay nanotubes were fabricated via activators regenerated by electron transfer for atom transfer radical polymerization (ARGET ATRP) by designing a water-soluble amphiphilic ATRP initiator that can adsorb onto imogolite surface in an aqueous solution.

نانوکامپوزیت‌های پلی‌استیرن/MCM–41 به روش پلیمرشدن رادیکالی انتقال اتم (ATRP) در دمای 110 درجه سلسیوس سنتز شدند. روش‌های آغاز فعال‌کننده‌هایی که با انتقال الکترون تولید می‌شوند (AGET) و فعال‌کننده‌هایی که با انتقال الکترون بازتولید می‌شوند (ARGET) به­ عنوان دو روش نوین آغاز در ATRP به­ کار گرفته شدند. ساختار ویژه، مساحت سطح، اندازه ذرات و توزیع آنها و ساختار اسفنجی و حفره‌ای نانوذرات MCM–41 سنت...

Journal: :Macromolecular bioscience 2014
Diane C Forbes Nicholas A Peppas

This work investigates the interactions of a polycationic nanocarrier with siRNA and with cells in order to better understand the capabilities and limitations of the carrier. The polycationic nanocarriers are cross-linked copolymer nanoparticles synthesized in a single-step reaction using ARGET ATRP (activators regenerated by electron transfer atom transfer radical polymerization). The polycati...

Journal: :Chemical communications 2008
François Stoffelbach Nebewia Griffete Chuong Bui Bernadette Charleux

This communication describes the first example of the efficient use of a simple amphiphilic molecule as both a surfactant and an initiator in the miniemulsion polymerization of methyl methacrylate under AGET and ARGET ATRP conditions.

ژورنال: :مجله علوم و تکنولوژی پلیمر 2015
خضراله خضری وحید حدادی اصل حسین روغنی ممقانی

نانوکامپوزیت های پلی استیرن/mcm–41 به روش پلیمرشدن رادیکالی انتقال اتم (atrp) در دمای 110 درجه سلسیوس سنتز شدند. روش های آغاز فعال کننده هایی که با انتقال الکترون تولید می شوند (aget) و فعال کننده هایی که با انتقال الکترون بازتولید می شوند (arget) به­ عنوان دو روش نوین آغاز در atrp به­ کار گرفته شدند. ساختار ویژه، مساحت سطح، اندازه ذرات و توزیع آنها و ساختار اسفنجی و حفره ای نانوذرات mcm–41 سنت...

Journal: :Macromolecules 2012
Daniel J Siegwart Matthias Leiendecker Robert Langer Daniel G Anderson

Conventional synthesis of polymers by ATRP is relatively low throughput, involving iterative optimization of conditions in an inert atmosphere. Automated, high-throughput controlled radical polymerization was developed to accelerate catalyst optimization and production of disulfide-functionalized polymers without the need of an inert gas. Using ARGET ATRP, polymerization conditions were rapidly...

2015
Anja C Pauly Katrin Schöller Lukas Baumann René M Rossi Kathrin Dustmann Ulrich Ziener Damien de Courten Martin Wolf Luciano F Boesel Lukas J Scherer

The grafting of poly(hydroxyethylmethacrylate) on polymeric porous membranes via atom transfer radical polymerization (ATRP) and subsequent modification with a photo-responsive spiropyran derivative is described. This method leads to photo-responsive membranes with desirable properties such as light-controlled permeability changes, exceptional photo-stability and repeatability of the photo-resp...

2015
Marcello Iacono Andreas Heise Walter Remo Caseri

The synthesis of polymer brush decorated silica nano-particles is demonstrated by activator regeneration by electron transfer atom transfer radical polymerization (ARGET ATRP) grafting of poly(tert-butyl methacrylate). ATRP initiator decorated silica nano-particles were obtained using a novel trimethylsiloxane derivatised ATRP initiator obtained by click chemistry. Comparison of de-grafted poly...

Journal: :Journal of polymer science 2021

Activators regenerated by electron transfer (ARGET) atom radical polymerization (ATRP)-based aqueous miniemulsion where the takes place in stabilized monomer droplets is described. In this work, we compared styrene, n-butyl methacrylate (nBMA) and tert-butyl (tBMA) investigated influence of their hydrophobicity on dispersity, molecular weight particle stability based partition coefficients (log...

Journal: :Reactive & Functional Polymers 2021

The first example of activators regenerated by electron transfer atom radical polymerisation (ARGET ATRP) under precipitation (PP) conditions is reported. This new method for polymer synthesis (called ARGET ATRPP) requires only very low levels metal catalyst success, a distinctive feature that enables the production uniform microspheres reversible-deactivation control. influence (monomer concen...

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