Citation Spinney, Heather A., Christopher R. Clough, and Christopher C. Cummins. “The Titanium Tris-Anilide Cation [Ti(N[[superscript t]Bu]Ar)[subscript 3]][superscript +] Stabilized as Its PerfluoroTetra-Phenylborate Salt: Structural Characterization and Synthesis in Connection with Redox Activity of 4,4-Bipyridine Dititanium Complexes.” Dalton Trans. 44, no. 15 (2015): 6784–6796. © 2015 Royal...

In the title complex, {[Ni(2)(C(14)H(4)N(2)O(8))(H(2)O)(6)]·2H(2)O}(n), the two Ni(II) atoms are located in different special positions (one on a twofold rotation axis and the second on a centre of symmetry) and have different distorted octa-hedral environments (one by two N atoms from a bipyridine unit, two O atoms from two water mol-ecules and two O atoms from two carboxyl-ate groups, and the...

A homochiral triple helix was self-assembled from an axially chiral bipyridine and a linear metal-connecting point, which further assembles into a 2D network via infinite pi...pi stacking interactions and acts as a host for the inclusion of guest molecules.

Rh(III) and Ir(III) can be complexed to bipyridine groups attached to the termini of bis(dioxaborine)-capped heptamethines; these chromophores exhibit large third-order polarisabilities at 1.55 μm, while retaining good film-forming properties and linear optical transparency in the near infrared.

The hydro-thermal reaction of cobalt nitrate with 4,4'-bipyridine and 3-nitro-benzoic acid lead to the formation of the title complex, [Co(C(7)H(4)NO(4))(2)(C(10)H(8)N(2))(2)](n). In the crystal structure, the Co(II) atoms are coordinated by two terminal carboxyl-ate anions and four 4,4'-bipyridine ligands within slightly distorted octa-hedra. The Co(II) atom and one of the two independent 4,4'...

This study was undertaken to evaluate the biological potency of two synthetic human growth hormone-releasing factors, hGRF (1-44)NH2 and hGRF (1-29)NH2, on growth hormone (GH) release in young dairy heifers (n = 10) and pigs (n = 10). In each species, the GH response to an iv injection (0, .067, .2, .6 and 1.8 nmol.kg-1 body weight) of each peptide was evaluated in a double 5 X 5 Latin square d...

A 2,2'-bipyridine-appended ferrocene rotor, 1,1'-di(5-yl-ethynyl-2,2'-bipyridine)ferrocene, can be switched from a folded/stacked (syn) conformation to an extended/unstacked (anti) conformation by the addition of [Cu(CH3CN)4](PF6) and 6,6'-dimesityl-2,2'-bipyridine. This extension and contraction process was completely reversible and could be triggered either chemically or electrochemically.

Understanding the formation of metal-molecule contact at microscopic level is key towards controlling and manipulating atomic-scale devices. Employing two isomers bipyridine, $4,{4}^{\ensuremath{'}}$ bipyridine $2,{2}^{\ensuremath{'}}$ between gold electrodes, here, we investigate a bond by studying charge transport through single molecular junctions using mechanically controlled break junction...

A novel heteroleptic ruthenium complex carrying a heteroaromatic-4,4'-pi-conjugated 2,2'-bipyridine [Ru(II)LL'(NCS)(2)] (L = 4,4'-bis[(E)-2-(3,4-ethylenedioxythien-2-yl)vinyl]-2,2'-bipyridine, L' = 4,4'-(dicarboxylic acid)-2,2'-bipyridine) was synthesized and used in dye-sensitized solar cells, yielding photovoltaic efficiencies of 9.1% under standard global AM 1.5 sunlight.

tow new compound of type [(chelate)2cu-oh-cu(chelate)2] x3.nh2o, where chelate=1,10-phenanthroline; x=cl¯(n=3.5) and chelate=4,4'-dimethyl-2,2'-bipyridine;  (n=5) have been synthesized and their properties investigated. the complexes show room temperature magnetic moment order of 1.0 b.m. per copper atom. the x-band esr spectrum of powdered samples at room temperature shows typical dm=1 transit...