The organization of magnetic nanorods in microphase-separated diblock copolymers composed of poly(styrene-b-2-vinylpyridine) (PS-PVP) as a function of rod length and rod concentration was investigated using both transmission electron microscopy and small-angle X-ray scattering. Our results reveal that the nanorods were sequestered into the PVP domains, which is attributed to the preferential in...

This work describes the synthesis and applications of amphiphilic polystyrene-block-poly(N-vinyl-2-pyrrolidone) (PS-b-PVP) copolymers as a silver and silica nanoparticle surface modification agent. The synthesis of PS-b-PVP was carried out using controlled/living radical polymerization techniques. The synthesis of the block copolymers was confirmed by gel permeation chromatography and hydrogen ...

A simple procedure is described to incorporate gold nanoparticles and control their location within symmetric poly(styrene-b-2 vinyl pyridine) (PS-PVP) diblock copolymers. Gold nanoparticles coated with thiol-terminated PS and/or PVP homopolymer chains (Mn approximately 1300 and 1500 g/mol, respectively) are incorporated into alternating lamellar layers of PS and PVP (total Mn approximately 196...

Polyvinyledenefluoride–polystyrene (PVDF/PS) blend ultrafiltration membranes were prepared using phase inversion technique. Casting solutions were prepared with different compositions of polyvinylidene fluoride (PVDF) and polystyrene (PS) both in the presence and absence of the additive, polyvinylpyrolidone (PVP) using dimethylacetamide as solvent. The effects of compositions of PS and concentr...

Differences in dialyzer design may have consequences for patient outcomes. We evaluated the comparative effectiveness of commonly used dialyzers with respect to measures of dialysis treatment, anemia management, inflammation, and dialyzer clotting. Patients receiving hemodialysis between January 1, 2009, and December 31, 2013, and using polyarylethersulfone-polyvinylpyrrolidone (PAS-PVP; Polyfl...

In this work, the structural features of spherical gold nanoparticles (NPs) decorated with highly grafted poly(styrene) (PS), poly(vinylpyridine) (PVP) and PS-PVP diblock copolymer brushes immersed in a good solvent are investigated by means of Dissipative Particle Dynamics (DPD) simulations as a function of grafted chain length and of homopolymer and copolymer chain composition. For NPs grafte...

This work presents the synthesis of polyvinylpyridine-polystyrene (PVP-b-PS) diblock copolymers via RAFT dispersion polymerization. Spin-coated PVP-b-PS films were converted into porous surfaces by a controlled alignment and swelling strategy.

A modified method based on in situ chemical reduction was developed to prepare mono-dispersed polystyrene/silver (PS/Ag) composite microspheres. In this approach; mono-dispersed PS microspheres were synthesized through dispersion polymerization using poly-vinylpyrrolidone (PVP) as a dispersant at first. Then, poly-dopamine (PDA) was fabricated to functionally modify the surfaces of PS microsphe...

We investigated the electrical stabilities of two types of pentacene-based organic thin-film transistors (OTFTs) with two different polymeric dielectrics: polystyrene (PS) and poly(4-vinyl phenol) (PVP), in terms of the interfacial charge depletion. Under a short-term bias stress condition, the OTFT with the PVP layer showed a substantial increase in the drain current and a positive shift of th...

Macrosurfactants consisting of water-soluble poly(vinylcaprolactam) (PVCap) or poly(vinylpyrrolidone) (PVP) segments with comparatively shorter hydrophobic poly(styrene) (PS) poly(2,3,4,5,6-pentafluorostyrene) (PPFS) were used as kinetic hydrate inhibitors (KHIs). These synthesized 2-cyanopropan-2-yl N-methyl-N-(pyridin-4-yl)dithiocarbamate switchable reversible addition–fragmentation chain tra...