The paper reports a process for synthesis of γ-alumina from kaolin. Kaolin was transformed to meta-kaolin by calcination at 800 ̊C for 2h. γ-alumina powder was synthesized through extracting alumina from metakaolin via H2SO4 and meta-kaolin reactions and consequently precipitation in ethanol, which led to form the aluminum sulfate. The precipitated aluminum sulfate was dried and calcined at 900 ̊...

In the present study, adsorption of Co(tsPc)-4 using γ-Alumina was investigated. γ-Alumina was prepared by gel combustion method. The XRD pattern revealed that the synthesized γ-Alumina is amorphous and SEM image showed its nanosize scale while BET surface area about 501 m2/g and pore size of 7 nm implies highly porous surface which is a characteristic property of a high-quality adsorbent. In t...

Copper oxide supported on γ-alumina nanoparticles were prepared and were well characterized. In this study catalytic activities of the supported copper oxide for oxidation of cyclohexene to 2-cyclohexene-1-ol, 2-cyclohexene-1-one and cyclohexene oxide with TBHP and H2O2 as the oxidant, in the liquid phase were considered. For the CuO/γalumina nanocomposites, acetonitrile as the solvent was empl...

An efficient and green protocol for the synthesis of αaminonitriles derivatives by one-pot reaction of different aldehydes with amines and trimethylsilyl cyanides has been developed using natural alumina, alumina sulfuric acid (ASA), nano-γ-alumina, nanoalumina sulfuric acid (nano-ASA) under microwave irradiation and solvent-free conditions. The advantages of methods are short reaction times, h...

Increasing uses of engineered nanoparticles (ENPs) in commercial products and industrial applications has eventually resulted to their releases into atmospheric, terrestrial, and aquatic environments. However, knowledge gaps in ENPs toxicity, fate, and behaviour currently limit our ability to quantify risk assessment of materials with nanoscale dimensions, and therefore, the extent of the resul...

in this work, boehmite sol was prepared by a previously applied and validated method; hydrolysis of aluminum chloride hexa-hydrate. in order to obtain precise results, the effect of ph after adding precipitating agent, aging time, peptizing temperature and ultrasonic vibration time on the crystallite size of final precipitate were investigated in a narrow range. the preparation conditions appli...

Alumina nanofibers were prepared by a technique that combined the sol-gel and electrospinning methods. The solution to be electrospun was prepared by mixing aluminum isopropoxide (AIP) in ethanol, which was then refluxed in the presence of an acid catalyst and polyvinylpyrolidone (PVP) in ethanol. The characterization results showed that alumina nanofibers with diameters in the range of 102 to ...

Significant progress has been made on the synthesis and application of mesoporous γ-alumina. To date, little attention has been paid to the synthesis of microporous crystalline alumina. Here, fabrication of microporous crystalline γ-alumina using a microporous covalent triazine framework (CTF-1) as a template is described. Microporous crystalline γ-alumina with a micro-meso binary pore system w...

A new rapid, very simple and one-step sol-gel strategy for the large-scale preparation of highly porous γ-Al₂O₃ is presented. The resulting mesoporous alumina materials feature high surface areas (400 m² g-1), large pore volumes (0.8 mL g-1) and the γ-Al₂O₃ phase is obtained at low temperature (500 °C). The main advantages and drawbacks of different preparations of mesoporous alumina materials ...

In the present investigation, γ-alumina nanoparticles with particle sizes less than 10 nm, high specific surface area (351 m2/g), high pore volumes and relatively narrow pore sizes distribution was prepared via sol-gel method in presence of aluminum isopropoxide as an aluminum precursor, distilled water, acetic acid as hydrolysis rate controller and tert-butanol as solvent. They had meso ...