In the present study, Au-V2O5 sensing material was tested as a electrode for developing mixed-potential ammonia gas sensors. The results of measurements indicated selective responses to NH3 while this selectivity highly dependent on temperature. Different V2O5 contents were in electrode. showed that by increasing content from 15 wt.% 50 wt.%, sensors could be achieved at 550 °C. Au-50 %V2O5 sen...

The catalytic oxidation of sulfur dioxide to sulfur trioxide over several binary (MxOy/TiO2) and ternary (V2O5/MXOY/TiO2) supported metal oxide catalysts was systematically investigated. The supported metal oxide components were essentially 100% dispersed as surface metal oxide species, as confirmed by Raman spectroscopy characterization. The sulfur dioxide oxidation turnover frequencies of the...

A new atomic layer deposition (ALD) process for V2O5 using ozone (O3) as oxidant has been developed that resulted in crystalline V2O5 thin films which are single-phase and orthorhombic on various substrates (silicon, Au-coated stainless steel, and anodic aluminum oxide (AAO)) without any thermal post-treatment. Within a fairly narrow temperature window (170−185 °C), this low temperature process...

Small addition of potassium to V/Ti-oxide catalyst (K:V=0.19), consisting of 3.7 monolayer VOx , increased activity and selectivity in partial oxidation of toluene. In order to elucidate the nature of vanadia species formed on the surface of V/Ti-oxide upon potassium doping, the catalysts were studied by transient kinetics method. The transient product responses during toluene oxidation by the ...

V2O5 xerogel films were fabricated by casting V2O5 sols onto FTO glass substrates and annealing at 300 C for 3 hours in nitrogen and air. The films annealed in nitrogen and air possessed different grain size and crystallinity. Optical absorption measurements and electrochemical impedance analyses revealed a reduced optical bandgap and enhanced electrical conductivity of N2 annealed V2O5 film. L...

Vanadium oxide (V2O5) is a material that can be fabricated as a thin film of only a few atomic layers thick during mechanical exfoliation due to the weak interlayer interactions, much like how graphene is created. During this project we looked at the band structure of both the bulk and mono-layered V2O5. We used computer software called ABINIT, which is installed on the high performance compute...

A series of supported V2O5/Al2O3 catalysts were synthesized by incipient wetness impregnation with vanadium isopropoxide in isopropanol solutions and subsequent calcination. The vanadium surface density was varied from 0.3 to 11.4 V atoms/nm2 spanning the sub-monolayer and above-monolayer regions. The resulting supported vanadium oxide catalysts were physically characterized with in situ Raman ...

We investigate the effect of interfacial buffer layers—vanadium oxide V2O5 and cesium carbonate Cs2CO3 —on the performance of polymer solar cells based on regioregular poly3-hexylthiophene and 6,6 -phenyl C60 butyric acid methyl ester blend. The polarity of solar cells can be controlled by the relative positions of these two interfacial layers. Efficient inverted polymer solar cells were fabric...

Growth and electrochemical properties of single-crystalline vanadium pentoxide (V2O5) nanorod arrays were investigated. Vanadium pentoxide nanorod arrays were grown by electrochemical deposition, surface condensation induced by a pH change and sol electrophoretic deposition. Uniformly sized vanadium oxide nanorods with a length of about 10 mm and diameters of 100 or 200 nm were grown over a lar...