Abstract A series of aryl sulfonic acids were tested as catalysts for acid hydrolysis occurring at the surface poly(ethylene) terephthalate (PET) particles. Specifically, p‐toluenesulfonic monohydrate (PTSA), 2‐naphthalenesulfonic (2‐NSA), and 1,5‐naphthalenedisulfonic tetrahydrate (1,5‐NDSA) chosen to provide active groups varying hydrophobic functionality. The effect catalyst concentration re...