Rapid separation and determination of mixtures of L-ascorbic acid, nitrite, sulfite, oxalate, iodide and thiosulfate by conventional ion chromatography is often difficult due to incomplete separation of L-ascorbic acid and nitrite from the water peak when using eluents giving short elution times for iodide and thiosulfate. Separation of the six species within about 15 min has been achieved by i...

Spectrophotometric Determination of Thiosulfate in Desulfurization Solutions by Decoloration Methylene Blue Published on: May 1, 2023 Xiuxiu Zhao, Ming Xu, Chunying Ma, Yingying Xianji Ma Spectroscopy, 2023, Volume 38, Issue 5 Pages: 19–22,34 This article proposes a method for the determination thiosulfate decoloring spectrophotometry with methylene blue as an oxidant. has redox properties. Its...

NOx emissions continues to be a major challenge in order reduce the environmental impact of thermal conversion non-recyclable waste and fuels with high nitrogen contents. Oxidation NO NO2 followed by absorption aqueous solutions sulfur compounds as additives has recently gained more attention from flue gases. One is consumption sulfite, requiring sulfite oxidation inhibitors such thiosulfate. T...

BACKGROUND Dinitrosyl nonheme-iron complexes can appear in cells and tissues overproducing nitric oxide. It is believed that due to their chemical nature these species may be implicated in certain pathophysiological events. We studied the possible role of low molecular mass dinitrosyl iron complexes in the control of noradrenaline release in electrically stimulated rat tail artery. RESULTS A ...

Cell-free extracts from several microorganisms, when prepared by methods originally devised for Chlorella pyrenoidosa (Emerson strain 3) and incubated anaerobically with ATP, Mg(2+), and 2, 3-dimercaptopropan-1-ol, are capable of reducing sulfate-(35)S to thiosulfate. These microorganisms include, in addition to C. pyrenoidosa (Emerson strain 3), several other strains of C. pyrenoidosa, Chlorel...

Reductive and oxidative pathways of the sulfur cycle were studied in a marine sediment by parallel radiotracer experiments with SO(4), H(2)S, and S(2)O(3) injected into undisturbed sediment cores. The distributions of viable populations of sulfate- and thiosulfate-reducing bacteria and of thiosulfate-disproportionating bacteria were concurrently determined. Sulfate reduction occurred both in th...

Thermophilic sulfide-producing microorganisms from an oil pipeline network were enumerated with different sulfur oxyanions as electron acceptors at 55°C. Most-probable number (MPN) analysis showed that thiosulfate-reducing bacteria were the most numerous sulfidogenic microorganisms in pipeline inspection gauge (PIG) scrapings. Thiosulfate-reducing and methanogenic enrichments were obtained from...

Two new dialkylammonium thiosulfates, namely bis(diisopropylammonium) thiosulfate, 2C(6)H(16)N(+)·S(2)O(3)(2-), (I), and bis(tert-butylammonium) thiosulfate, 2C(4)H(12)N(+)·S(2)O(3)(2-), (II), have been characterized. The secondary ammonium salt (I) crystallizes with Z = 4, while the primary ammonium salt (II), with more hydrogen-bond donors, crystallizes with Z = 8 and a noncrystallographic ce...

Hydraulic fracturing of black shale formations has greatly increased United States oil and natural gas recovery. However, the accumulation of biomass in subsurface reservoirs and pipelines is detrimental because of possible well souring, microbially induced corrosion, and pore clogging. Temporal sampling of produced fluids from a well in the Utica Shale revealed the dominance of Halanaerobium s...

Various cultures (previously described), which oxidize thiosulfate in mineral media have been studied in an attempt to determine the products of oxidation. The transformation of sodium thiosulfate by Cultures B, T, and K yields sodium tetrathionate and sodium hydroxide; secondary chemical reactions result in the accumulation of some tri- and pentathionates, sulfate, and elemental sulfur. As a r...