The syntheses of five homoleptic copper(I) complexes [CuL2][PF6] are described in which L is a 4,4'-di(4-bromophenyl)-6,6'-dialkyl-2,2'-bipyridine ligand (compounds 1-4 with methyl, (n)butyl, (iso)butyl and hexyl substituents, respectively) or 4,4'-di(4-bromophenyl)-6,6'-diphenyl-2,2'-bipyridine (5). The new ligands 2-5 and copper(I) complexes [CuL2][PF6] (L = 1-5) have been fully characterized...

A di-vanadium-substituted Lindqvist-type polyoxometalate [Cu(C12H8N2)2]2[V2W4O19]·4H2O (1) was hydrothermally synthesized and characterized structurally by single crystal X-ray diffraction analysis. X-ray photoelectron spectroscopy and energy disperse spectroscopy tests further prove the existence of vanadium. Ultraviolet photoelectron spectroscopy and density functional theoretical studies ind...

We report a pump-probe spectroscopy study of electron injection rates in dye-sensitized solar cell (DSSC) devices. We examine the case of working devices employing an N719 ruthenium sensitizer and an iodide electrolyte. Electron injection is found to occur mainly on a sub-100 fs time scale, followed by a slower component with a lifetime of 26.9 ps, in accordance with previous reports on model s...

With the emergence of Internet Things, dye-sensitized photovoltaics (DSPVs) have attracted considerable interest for indoor energy harvesting over past decade. In this study, a cosensitization approach is applied by mixing ruthenium-based dyes to achieve an increased DSPV performance under low-intensity light conditions. The optimized cosensitized exhibits excellent power-conversion efficiency ...

Dye-sensitized solar cells are currently under intense academic and industrial investigation, owing to their great potential to serve as a low-cost alternative to existing photovoltaic technologies. This paper puts forward a method, which adopts heterocyclic substituted triarylamine units as electronic donor moieties, to design triarylamine dyes for efficient dye-sensitized solar cells. Three n...

Abstract Ensuring high power conversion efficiency, partially or completely replacing Pt electrodes with inexpensive materials is one of the important development directions dye-sensitized solar cells (DSSCs). In this work, we have developed a three-component (MWCNTs, carbon black and graphite) (tri-carbon) electrode material for DSSC devices combined advantages electron transfer kinetics MWCNT...

New alcohol-soluble conjugated small molecule electrolytes (CSMEs), 3,6-bis-(5-benzoic acid-thiophen-2-yl)-2,5-bis-(2-ethylhexyl)-2,5-dihydro-pyrrolo[3,4-c]pyrrole-1,4-dione liquid crystalline (DPP-COOH) and di-tetrabutylammonium cis-bis(isothiocyanato)bis(2,2'-bipyridyl-4,4'-dicarboxylato)ruthenium(II) dye (N719), are developed as interfacial modification in inverted polymer solar cells (PSCs)...

A detailed theoretical investigation of one dimensional SiO2/TiO2 photonic crystal based ZnO-Pt dye sensitized solar cell with N719 is carried out. The optical properties the theoretically designed such as transmittance, absorptance and reflectance are calculated using transfer matrix method in order to calculate numerically key parameters like open circuit voltage (VOC), short current (Jsc) ef...