the silica boron sulfuric acid nanoparticles (sbsans) as an efficient heterogeneous solid acid catalyst with both brønsted and lewis acidic sites catalyzed the preparation of bis-4-hydroxycoumarin derivatives using reaction of aldehydes and 4-hydroxycoumarin under mild and solvent-free condition at room temperature. this new and efficient methodology has advantages in comparison with currently ...

The electron capture gas liquid chromatography test method for chick edema factor has been modified by replacing the alumina column s t ep with an additional sulfuric acid cleanup and a caustic wash which permits a reduction in sample cleanup time. Samples are subjected to double preliminary sulfuric acid cleanup and caustic wash and extracted each time with t r imethyl pentane. The final extra...

TiO2 nanoparticles were synthesized from titanium isopropoxide by a simple peptization method using sulfuric, nitric, and acetic acids. The effect of peptizing acid on physicochemical and photocatalytic properties of TiO2 powders was studied. The structural properties of synthesized TiO2 powders were analyzed by using XRD, TEM, N2-physisorption, Raman, DR UV-vis, FTIR, and X-ray photoelectron s...

A number of the components of the tissues contain in their molecules either phosphoric or sulfuric acid. The phosphoric acid radicle is contained in the monoand polynucleotides, and the sulfuric acid radicle in chondroitinand mucoitin-sulfuric acids. In all these compounds the acid radicle is linked in ester form to either a carbohydrate or a polyhydric alcohol. On long acquaintance with substa...

[reaction: see text] The reaction of CH(4) with CO(2) has been performed in anhydrous acids using VO(acac)(2) and K(2)S(2)O(8) as promoters. NMR analysis establishes that the primary product is a mixed anhydride of acetic acid and the acid solvent. In sulfuric acid, the overall reaction is CH(4) + CO(2) + SO(3) --> CH(3)C(O)-O-SO(3)H. Hydrolysis of the mixed anhydride produces acetic acid and t...

formaldehyde in small quantities is commonly analyzed by spectrophotometric methods. one of the most-commonly used spectrophotometric techniques for this purpose is based on the reaction with chromotropic acid. because of its simplicity, sensitivity, selectivity and its low cost, it is still widely used. investigations for replacing the concentrated sulfuric acid with other acids or using more ...

sugarcane bagasse contains cellulose, lignin and hemicellulose, 39-42%, 20-25% and 25-27% respectively. so it is can be used as a sugar source in many processes. lignin and hemicellulose must be removed before hydrolysis of cellulose. several different pretreatment approaches have been studied. the purpose of this research is comparison of acid, ozone and combination of ozone-acid as pretreatme...

Recent studies suggest that dimethylamine could be a key ternary species in the formation and early growth of atmospheric aerosol particles. We report on nucleation studies for the ternary system of sulfuric acid, water and dimethylamine which have been performed at the CERN CLOUD chamber. These studies were conducted at atmospherically relevant concentrations of sulfuric acid and dimethylamine...

An efficient and green protocol for the synthesis of αaminonitriles derivatives by one-pot reaction of different aldehydes with amines and trimethylsilyl cyanides has been developed using natural alumina, alumina sulfuric acid (ASA), nano-γ-alumina, nanoalumina sulfuric acid (nano-ASA) under microwave irradiation and solvent-free conditions. The advantages of methods are short reaction times, h...