The electroreduction mechanism of 1-Br-2-naphtol and 1-I-2-naphtol, two inherently chiral BINOL derivatives ([1,1′-Binaphthalene]-2,2′-diol, 6,6′-dibromo 1,1′-Binaphthalene,6,6′-dibromo-2,2′-dimethoxy; in the following named P1 P2, respectively), is characterized by means an integrated electrochemical theoretical approach. experimental characterization based on cyclic voltammetry measurements. ...