Aromatics growth beyond 2-, 3-ring PAH is analyzed through a radical-molecule reaction mechanism which, in combination with a previously developed PAH model, is able to predict the size distribution of aromatic structures formed in rich premixed flames of ethylene at atmospheric pressure with C/O ratios across the soot threshold limit. Modeling results are in good agreement with experimental da...

The emission of solid carbonaceous particulate matter (i.e. soot) is a world-wide problem that effects both human health and global environmental health alike. Although a number of sources contribute to the concentration of soot in the atmosphere, Diesel engines play a significant role. Diesel engines, or direct-injection compression-ignition engines, are the primary power plant for delivering ...

Introduction. During the combustion of diesel fuel in a engine with an increased supply, as result its incomplete combustion, soot particles are formed, which either released into atmosphere or inevitably enter oil. Soot, polluting oil, causes change quality indicators. Soot is very small formed by complex reaction mechanism flame fuel-rich region during hydrocarbons absence air, mainly consist...

Increased understanding is needed with respect to soot formation from high pressure diesel sprays as emissions standards become increasingly stringent and require complex methods for its reduction. Understanding soot formation and its spatial distributions is necessary to advance fundamental spray combustion knowledge. Given that the underlying nature of high pressure combusting diesel sprays r...

Engineering the interface between different components of heterogeneous catalysts at nanometer level can radically alter their performances. This is particularly true for ceria-based catalysts where the interactions are critical for obtaining materials with enhanced properties. Here we show that mechanical contact achieved by high-energy milling of CeO2-ZrO2 powders and carbon soot results in t...

Nanocrystalline La2Sn2O7 and La2Sn1.8Co0.2O7 with a phase-pure pyrochlore structure were synthesized by a hydrothermal method, and their catalytic activity was investigated for soot combustion. The as-synthesized catalysts presented relatively larger surface area, and pore volume, which was benefit to the gas molecule diffusion in the reaction. A uniform spherical structure with particle size o...

A methodology for estimating the extinction factor at λ = 530 nm in diffusion flames is presented. All experiments have been in microgravity and have as their objective the production of quantitative data that can serve to evaluate the soot volume fraction. A better understanding of soot formation and radiative heat transfer is of extreme importance to many practical combustion related processe...