A degradation study of polystyreneepolybutadieneepolystyrene and polyisopreneepolystyrenee polyisoprene in both dichloromethane and hexane solvents is presented. Alternative solvents for metathetic degradation provide the potential for greener chemistry, better selectivity, and control over the products. The catalyst concentration and solvent selection both determine the products formed. The de...

The profitability impacts of solvent storage are modeled for new coal and natural gas-fired power plants with amine and ammonia-based post-combustion CCS facing variable electricity prices. With perfect information of future prices, up to 3 hours of solvent storage was valuable due to price volatility at carbon prices up to $40/tonne CO2 and no regenerator undersize. With imperfect information ...

The present study was designed to evaluate the performance of alternative bio-based solvents, more especially 2-methyltetrahydrofuran, obtained from crop's byproducts for the substitution of petroleum solvents such as hexane in the extraction of fat and oils for food (edible oil) and non-food (bio fuel) applications. First a solvent selection as well as an evaluation of the performance was made...

This Application Note demonstrates the use of the Agilent 1260 Infi nity Analytical SFC Solution for method screening for the separation of enantiomers. To enhance the 1260 Infi nity SFC Solution for method development and screening, a second thermostatted column compartment and two column selection valves were added for column selection, together with a 12-position/13-port valve for solvent se...

A survey is given on our attempts to calculate equilibrium properties of molecular liquids (pure solvents and electrolyte solutions) with the help of spatial pair correlation functions, starting from classical molecular pair interactions. The selection of potential models, especially the influence of molecular polarizability, is discussed as well as the limitations of the different methods of c...

MOTIVATION It is widely known that terminal residues of proteins (i.e. the N- and C-termini) are predominantly located on the surface of proteins and exposed to the solvent. However, there is no good explanation as to the forces driving this phenomenon. The common explanation that terminal residues are charged, and charged residues prefer to be on the surface, cannot explain the magnitude of th...

Pressurized liquid extraction (PLE) was evaluated as a method for extracting semivolatile organic compounds (SOCs) from air sampling media, including quartz fiber filter (QFF), polyurethane foam (PUF), and a polystyrene divinyl benzene copolymer (XAD-2). Hansen solubility parameter plots were used to aid in the PLE solvent selection in order to both reduce coextraction of polyurethane and save ...

This presentation discusses the use of an interval analysis based global optimization approach for the systematic design of cleaning solvent blends (commonly referred to as blanket washes) for lithographic printing. The simultaneous consideration of associated process constraints, property requirements, and environmental restrictions makes the blanket wash design a rather difficult problem. To ...