Two thioxanthone-based fluorescent probes exhibited prominent solvatofluorochromism, and they were further found to be useful as fluorescence indicators for the qualitative and quantitative detection of low-level water content in various solvent media.

The solvatochromic photophysical properties of two fluorescent, cyano-substituted BODIPY dyes-8-(4-bromophenyl)-3,4,4,5-tetracyano-4-bora-3a,4a-diaza-s-indacene (4CN) and 8-(4-bromophenyl)-3,5-dicyano-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (2CN)-have been studied in various solvents by UV-vis spectrophotometry and steady-state and time-resolved fluorometry. These two BODIPY analogues have c...

Allochroic organic light-emitting devices (AOLEDs) characterized by field-dependent emissive color variation are promising as visible signal response units for intelligent applications. Most of the AOLEDs were realized by changing their recombination zones or inter- and intramolecular energy transfer, rendering the limited repeatability, stability, and electroluminescence (EL) performance. We r...

heterogeneous catalytic hydrogenation of cyclohexene, catalyzed by pt/a1203, was carried out in thirteenvarious solvents (four alcoholic solvents, six aprotic polar solvents and three non polar solvents) at 25 °c.single-parameter correlations of logk vs. normalized polarity parameter (etn), hydrogen-bond acceptorbasicity (p), hydrogen-bond donor acidity (a) and dipolarity/polarizibility (it*) d...

Thiophene-linked π-conjugate shows better solvatochromic redshift and AIE-features than furan-analog. Yet, furan-linked is a solid-state emitter with reversible mechanofluorochromic features. Variations in crystal packing play crucial role this disparity.

Central to major advances in biochemical assays, molecular sensor technologies, and molecular optical imaging are fluorescent materials that provide high detection sensitivity for molecular processes. In biological optical imaging, the low tissue autofluorescence and the deep penetration of light into the tissues observed at wavelengths between 650 and 900 nm allow the use of near-infrared (NIR...

However, the application of such dyes in aqueous solution turned out to be appreciably more difficult. Strongly hydrophilic groups such as sulfonic acid groups, polyether groups, and pyridyl substituents, basically induce water solubility of 1; however, these materials exhibit a strong tendency to aggregate in the highly hydrophilic medium. Moreover, such dyes exhibit a high aptitude for the co...

An expression of unexpected simplicity is derived for the shift in optical transition energies of solute molecules in nonpolar solvents. The expression reveals a new spectroscopic rule that says: The higher the excited state of the solute, the larger the solvatochromic red shift. A puzzle formulated >50 years ago by Bayliss is solved. Bayliss, based on arguments from classical physics, assumed ...

We investigate the OH stretch vibrational frequency shifts of a prototype photoacid, 2-naphthol (2N), when dissolved in solvents of low polarity. We combine femtosecond mid-infrared spectroscopy and a theoretical model based on the Pullin-van der Zwan-Hynes perturbative approach to explore vibrational solvatochromic effects in the ground S(0) and the first electronically excited (1)L(b) states....

Nicotinonitrile chromophores with two tunable functions, excellent photophysical properties and solvatochromic behaviour can be prepared quickly and efficiently by microwave-assisted tandem oxidation/Bohlmann-Rahtz heteroannulation followed by copper(I)-mediated N-arylation.