This study presents methods for treating a kind of nanoclay and investigates the effects of methylaluminoxane (MAO) exposure time and or dodecylamine (DDA) reflux time on in-situ polymerization of ethylene in the presence of nanoclay and examines the morphology and properties of the prepared polyethylene/clay nanocomposites. The results revealed that by increasing MAO exposure time productivity...

One approach for making inexpensive inorganic-organic hybrid photovoltaic (PV) cells is to fill highly ordered TiO(2) nanotube (NT) arrays with solid organic hole conductors such as conjugated polymers. Here, a new in situ UV polymerization method for growing polythiophene (UV-PT) inside TiO(2) NTs is presented and compared to the conventional approach of infiltrating NTs with pre-synthesized p...

An in situ composite synthesis technique has been developed by grafting polystyrene chains onto single-wall carbon nanotubes (SWNTs) via a single-step debundling/polymerization scheme. The method, based on established anionic polymerization techniques, eliminates the need for nanotube pretreatment prior to functionalization and allows attachment of polymer molecules to pristine tubes without al...

We propose a non-equilibrium electrokinetic (EK) mixer with a nanoporous membrane fabricated on a microfluidic chip by laser polymerization technique. A non-equilibrium EK mixer had an array of nanochannels to generate a vortex using ion depletion and consequent electroconvection [1]. The nanochannels, however, require expensive and complicated fabrication processes. On the other hand, the lase...

Styrene-acrylate copolymer was synthesized in presence of carbon black through heterogeneous polymerization. The percentage of monomer conversion was measured by gravimetric method, also PSA, SEM, DSC and GPC were used for studying the particle size and particle size distribution, morphology, thermal properties and molecular weight, respectively. As well as color properties were characterized b...

A series of experiments on the synthesis of poly (ethylene terephthalate) (PET)/organo-montmorillonite (MMT) nanocomposites were carried out in a pressurized reactor using alkyl ammonium exchanged smectite clays, (Closite 30B).Given the degradation of organoclay at high temperatures, the in situ polymerization process was carried out at mild temperatures ranging from 210 to 230°C for 40 minutes...

“In situ” polymerization method was used to develop PANI-PSSA /textile. Polyaniline doped with polystyrene sulfonic acid (PANI-PSSA) as coatings for textiles were obtained by aqueous and emulsion route. The route uses chloroform solvent. Polymerization has been achieved in one step on the wool or polyamide textiles. For coated uncoated textiles, dried at room temperature, characterized structur...

There are described nanocomposites based on ultra high molecular weight polyethylene and graphite nanoplates prepared by in-situ polymerization method. It is carried out a comprehensive study of electric properties of these composites, including direct current (dc) and alternating current (ac) properties. There is explored dependence of the conductivity and dielectric permeability on filler con...

PSU/MMT nanocomposites are prepared by dispersing MMT nanolayers in a PSUmatrix via in situ photoinduced crosslinking polymerization. Intercalated methacrylate-functionalized MMT and polysulfone dimethacrylate macromonomer are synthesized independently by esterification. In situ photoinduced crosslinking of the intercalated monomer and the PSU macromonomer in the silicate layers leads to nanoco...