The silica boron sulfuric acid nanoparticles (SBSANs) as an efficient heterogeneous solid acid catalyst with both Brønsted and Lewis acidic sites catalyzed the preparation of bis-4-hydroxycoumarin derivatives using reaction of aldehydes and 4-hydroxycoumarin under mild and solvent-free condition at room temperature. This new and efficient methodology has advantages in comparison with currently ...

DETERMINATION OF SILICA OXIDE iron ores usually are found in intimate association with sllica and phosphorus compounds. heir quantitative separation and purification sometimes present difficult problems to the chemist. Silicic acids may represent various degrees of dehydration. They are exceedingly weak, but combine with metallic oxides and form some of the most stable , oxides in nature, the s...

3,4-dihydropyrimidin-2(1h)-thiones were synthesized in the presence of ag nanoparticle/melamine sulfonic acid (msa) supported on silica gel. the reaction was carried out at 110 oc for 20 min under solvent free conditions. in all cases, the three component reaction proceeded smoothly to give the corresponding 3,4-dihydropyrimidin-2(1h)-thiones in moderate to good yield. we have found the best co...

Selected alkaloids are chromatographed on cyanopropyl-silica thin layers using various nonaqueous and aqueous eluents. Because of the strong retention of these basic compounds, nonaqueous eluents containing medium polar diluents, strongly polar modifiers, and silanol blockers (ammonia or diethylamine) are required for separation. Likewise, aqueous eluents containing modifiers (acetonitrile, met...

In this study, an electrochemical sensor based on a boron doped diamond electrode (BDDE) was developed for the determination of naproxen (NAP) using poly(aniline-2-sulfonic acid)/boron electrode, p(A2SA/BDDE). Polymerization A2SA conducted in water/acetonitrile (1:1) mixture containing 0.1 M sodium perchlorate (NaClO4) bare BDDE and properties studied by cyclic voltammetry ferricyanide/KNO3 sol...