Leucinostatin, a peptide antibiotic, was separated by silica gel and alumina column chromatography into two related components designated as leucinostatin A hydrochloride (C61H111-N11O13.HCl) and leucinostatin B hydrochloride (C61H109N11O13.HCl). Physico-chemical as well as biological properties of the two separated components were analyzed. These properties pointed to closely resembling chemic...

Mesoporous templated MCM-48 silica was prepared using a C16 surfactant as template. The MCM-48 powders and thin films were characterized by different techniques. Two types of porous supports were used, namely macroporous α-alumina and silicon microsieves. The supported MCM-48 layers were applied as liquid permeable membranes in pressure-driven nanofiltration and electric field-mediated ion tran...

This study investigates the effect of carbide particle size on the microstructure, mechanical properties, and abrasive wear resistance of WC-17%Co HVOF-sprayed coatings. The characteristics of WC-1, WC-2, and WC-3 coatings with carbide sizes of 1 µm, 0.9 µm, and 0.5 µm, respectively, were also investigated. WC-1 coating experienced the maximum carbon loss of 42%, while WC-2 and WC-3 coatings un...

Ash sintering is an essential factor for the competitiveness of biomass gasification. Compared to conventional air gasification, gasification temperature reduced in auto thermal as utilisation compensation CaO carbonation reaction, which ultimately could suppress extent ash sintering. This work firstly investigated inhibition effect this process on simulated ashes (silica, potassium oxide and a...

A well-designed type of ultrathin carbon shell coating a silver core was prepared for the first time through an alternate adsorption and carbonization method. The obtained ultrathin carbon shell shows prominent advantages, including sufficient uniformity, better chemical stability than silica or alumina, biocompatibility, being free of pin-holes and low cost.

We report a method for the preparation of silica-coated molecular crystal nanorods. A sol-gel method was used to make silica nanotubes inside anodized alumina templates. The nanotubes were then loaded with 9-anthracene carboxylic acid (9-AC) and solvent annealed to produce silica-coated organic nanorods. The core-shell structure was confirmed using electron microscopy, and the highly crystallin...

The interaction of chromium oxide with Alz03, TiOz and SiO? supports is investigated with Raman spectroscopy. The influence of the nature of the oxide support, calcination temperature and chromium oxide loading upon the molecular state of the supported chromium oxide is determined. The Raman studies reveal that the oxide supports stabilize the chromium oxide as Cr(V1) in tetrahedral coordinatio...

Iron oxides catalyze the conversion of hydrogen peroxide (H(2)O(2)) into oxidants capable of transforming recalcitrant contaminants. Unfortunately, the process is relatively inefficient at circumneutral pH values because of competing reactions that decompose H(2)O(2) without producing oxidants. Silica- and alumina-containing iron oxides prepared by sol-gel processing of aqueous solutions contai...

OBJECTIVES Five commercial dental silanes were evaluated in vitro as adhesion promoters bonding a luting cement to silica-coated titanium surfaces. METHODS Titanium slides (n=20) were cleaned with alumina sand and then silica-coated with a special sand consisting of alumina particles coated with silica. The bonding of a resin composite cement (3M ESPE, Seefeld, Germany) to silica-coated and s...

A new regulation has been proposed that would lower the acceptable level of arsenic in drinking water from the current standard of 50 ppb. Therefore, research into effective arsenic removal treatment is important, especially for hard to treat waters with high concentrations of silica. The first phase of research was designed to determine if sand ballasted coagulation is a viable means of removi...