Recently we have reported on a hitherto unknown modification of human serum albumin of which the outstanding properties are electrophoretic homogeneity at pH 4.0 and its transformation to an electrophoretically heterogeneous form (2). In continuation of this study, the question was asked whether the ordinary human serum albumin (Fraction V), known to bc electrophoretically heterogeneous at pH 4...

Despite extensive surveys of extragalactic TeV gamma-ray candidates only 3 sources have so far been detected. All three are northern hemisphere objects and all three are low-redshift X-ray selected BL Lacs (XBLs). In this paper we present the results of observations of the three nearest southern hemisphere XBLs (PKS0548−322, PKS2005−489 and PKS2155−304) with the CANGAROO 3.8m imaging telescope....

Yet each in itself – this was the uncanny, the antiorganic, the life-denying character of them all – each of them was absolutely symmetrical, icily regular in form. They were too regular, as substance adapted to life never was to this degree – the living principle shuddered at this perfect precision, found it deathly, the very marrow of death – Hans Castorp felt he understood now the reason why...

The theory of optical activity presented in an earlier paper has been applied to helical structures, obtaining a compact formula for the residue rotation [ m ' ] ^ . In particular, the theory has been applied to the a-helix, and this theory consists of two parts: firstly the calculation of the magnitude and orientation of the polarisability tensor ellipsoid of the peptide residue from the locat...

A 32-year-old lady presented to our clinic with persistent painful restriction of her dominant forearm movements for three months after tension band wiring of olecranon. She had full elbow flexion and extension; however, her forearm rotations were restricted and painful. Investigations revealed prominent tips of the wire, eroding the radial tuberosity with heterotopic ossification between the r...

Cycloaddition of 3,4-dibromofuran with azo diesters proceeds by a Diels–Alder reaction followed by a novel rearrangement to give 3,5dibromotetrahydropyridazin-4-ones. Variable-temperature NMR spectroscopy shows four separate conformations at low temperature attributed to restricted rotation about the carbamate functions. The ethyl compound decomposes upon storage with loss of the carbamate grou...

Bent-core molecules with a linear alkyl chain in the bay position (anchor shaped molecules) form new liquid crystalline phases combining periodicities with different coherence lengths in distinct directions; in these LC phases the molecules are organized on average orthogonal in modulated layers (ribbons or patches) with restricted rotation around the long axis, thus representing modulated SmA(...

A new class of enantiopure carbene precursors based on cheap camphor has been developed, and a restricted rotation of one N-substituent due to the C-10 methyl group of the camphor skeleton has been found; in situ prepared corresponding carbenes revealed the same behaviour.

A crown ether-functionalized poly(tetraphenylethene) (AP-TPE) is synthesized and the rotation of the TPE group is successfully restricted via the complexation of crown ether and organic ammonium salts, leading to a stepwise enhanced fluorescence accompanied by a morphological transition from micellar to vesicular.