The X-ray crystal structure of 1,12-dodecane diammonium (C(12)DA(2+)) encapsulated in cucurbit[8]uril reveals an unconventional U-shaped conformation of C(12)DA(2+), which is attributed to the favorable host-guest interactions to overcome the charge-charge repulsion of the two ammonium groups in close proximity and high internal strain.

Resonant soft X-ray Raman scattering measurements on NiO have been made at photon energies across the Ni 2p absorption edges. The details of the spectral features are identified as Raman scattering due to d−d and charge-transfer excitations. The spectra are interpreted within the single impurity Anderson model, including multiplets, crystal-field and charge-transfer effects. At threshold excita...

Three custom-made Al0.2Ga0.8As p-i-n mesa X-ray photodiodes (200 μm diameter, 3 μm i layer) were electrically characterised and investigated for their response to illumination with soft X-rays from an Fe radioisotope X-ray source (Mn Kα = 5.9 keV; Mn Kβ = 6.49 keV). The AlGaAs photodiodes were shown to be suitable for photon counting X-ray spectroscopy at room temperature. When coupled to a cus...

In pursuit of creating cuprate-like electronic and orbital structures, artificial heterostructures based on LaNiO3 have inspired a wealth of exciting experimental and theoretical results. However, to date there is a very limited experimental understanding of the electronic and orbital states emerging from interfacial charge transfer and their connections to the modified band structure at the in...

The exposure of pyroelectric crystals to a heating cycle in near-vacuum conditions has been shown to be a viable method of producing x-rays. The z-negative face of the crystal forms a positive charge as the crystal heats, and a negative charge as it cools. The opposite is true for the z-positive face. Literature has shown that this charge is great enough to accelerate electrons to energies of u...

X-ray spectroscopy studies of potassium intercalated metal-free phthalocyanine multilayers adsorbed on Al(110) have been undertaken. Photoelectron spectroscopy measurements show the presence of several charge states of the molecules upon K intercalation, due to a charge transfer from the alkali. In addition, the comparison of valence band photoemission spectra with the density functional theory...

Sphere-like cadmium molybdate (CdMoO4) nanostructures have been synthesized by a large scale and simple sonochemical method by using Cd(Sal)2 (Sal=salicylidene) and Na2MoO4.2H2O for the first time. The effects of sonochemical irradiation time, sonochemical power, temperature, solvent, surfactant and cadmium source were considered to obtain a controlled shape. The as-prepared nanostructured cadm...

Diluted magnetic semiconductors (DMSs) are semiconductors alloyed with magnetic elements [1]. The physical properties of these materials can be tuned by both charge and spin, thus, they have great potential of being used in a wide variety of spintronic applications, such as magneto-optical, magneto-electrical, and magneto-transport devices. Spintronics (spin+electronics) is the technology that ...

Recently, Prussian blue analogues (PBAs) have been reported to exhibit a low voltage charge/discharge behavior with high capacity (300–545 mAh/g) in lithium-ion secondary batteries (LIBs). To clarify the mechanism of low voltage behavior, we performed ex situ synchrotron radiation X-ray diffraction (XRD) and ex situ X-ray absorption spectroscopy (XAS) of a film of Na1.34Mn[Fe(CN)6]0.84·3.4H2O w...

We present the first steps of a design of the optimal parameters for a full Bragg X-Ray free electron laser (BX-FEL). Aiming towards a future source of coherent X-ray radiation, operating in the strong Compton regime, we envisage the system to be the seed for an advanced light source or compact medical X-ray source. Here we focus on the design of the accelerator parameters: maximum gradient, op...