نتایج جستجو برای: quasi reversible reduction
تعداد نتایج: 621022 فیلتر نتایج به سال:
EEcient product form solution is one of the major attractions of queueing networks for performance modelling purposes. These models rely on a form of interaction between nodes in a network which allows them to be solved in isolation, since they behave as if independent up to normalisation. Markovian process algebras (MPA) extend classical process algebras with information about the duration of ...
Optically clear and stable dispersions of brightly photoluminescent Si nanoparticles were obtained by covalent attachment of alkenoic compounds to the particles. Quenching of photoluminescence by ethylamine, diethylamine, triethylamine, pyrazine, and piperazine was investigated. The photoluminescence was quenched by the action of these nitrogenous species, but in some cases could be partially r...
Given a group-invariant quasi-free state on the algebra of canonical commutation relations (CCR), we show how group averaging techniques can be used to obtain a symmetry reduced CCR algebra and reduced quasi-free state. When the group is compact this method of symmetry reduction leads to standard results which can be obtained using other methods. When the group is non-compact the group averagin...
Toric differential inclusions play a pivotal role in providing rigorous interpretation of the connection between weak reversibility and persistence mass-action systems polynomial dynamical systems. We introduce notion quasi-toric inclusions, which are strongly related to toric inclusions, but have much simpler geometric structure. show that every inclu...
ABSTRACT Four new copper complexes based on bidentate imino phenoxide ligands were synthesized and characterized by IR, UV-Vis spectroscopy, ESI mass spectrometry, single crystal X-ray diffraction, and electrochemistry. The crystal structures revealed that the copper(II) atoms are surrounded by phenolate oxygen and imine nitrogen atoms of two ligands in a distorted square-planar geometry. The e...
We study Hamiltonian dynamics of a Fermi–Pasta–Ulam (FPU) chain with bi-stable elements. We show, that a quasi-static driving of a ‘cold’ chain beyond the spinodal threshold leads to complex dynamical behavior involving equipartition which suggests thermalization. The subsequent quasi-static cycling between the two energy wells produces reversible temperature oscillations which we link to the r...
We introduce the notion ofstrongly $alpha$-reversible rings which is a strong version of$alpha$-reversible rings, and investigate its properties. We firstgive an example to show that strongly reversible rings need not bestrongly $alpha$-reversible. We next argue about the strong$alpha$-reversibility of some kinds of extensions. A number ofproperties of this version are established. It is shown ...
the reduction process for some quinones has been studid by cyclic voltammeby, rotating disk electrode voltammetry and chronopotentiometry in chloroform at platinum, gold and glassy carbon electrodes using tetrabutylmonium perchlorate (tb ap) as supporting eiectrolyte. the results obtained from this study reveal that the reduction of the quinones is two one-electron processes, the first reductio...
N-Substituted 4-benzoylpyridinium monocations form stable host-guest complexes with cucurbit[7]uril (CB[7]) in DMSO (K(eq) approximately 0.6-1.9 x 10(3) M(-1)). Observation of simultaneous reversible and quasi-reversible e-transfer processes from the free and intercalated quests, respectively, is attributed to the pre-e-transfer host-guest equilibrium. The standard rate constant for Me-BP@CB[7]...
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