Various inhibitors of metallo-beta-lactamases have been reported; however, none are effective for all subgroups. Those that have been found to inhibit the enzymes of subclass B2 (catalytically active with one zinc) either contain a thiol (and show less inhibition towards this subgroup than towards the dizinc members of B1 and B3) or are inactivators behaving as substrates for the dizinc family ...

The electrochemical corrosion behaviour of mild steel embedded in concrete, and partially immersed in 0.2M H2SO4, was studied in this investigation at ambient temperature by potential monitoring technique. The experimental work was performed with a digital multimeter and a Cu/CuSO4 electrode (CSE) as the reference electrode. Extracts of carica papaya leaves and sodium nitrite (NaNO2) in differe...

The corrosion inhibition performance of acetylacetonate complexes of zinc(II), manganese(II), cobalt(II) and copper(II) on the mild steel substrate in 1M H3PO4 was studied using DC polarization. It was seen that the mentioned complexes decreased corrosion rate of mild steel in phosphoric acid media due to the adsorption on metal surface. The potential of mild steel shifted toward more active po...

This study has investigated the solubility of inhibiting pigments and also the leaching behaviour of corrosion inhibitors from a polyester binder in an acid rain solution. This study has relevance to the control of cut-edge corrosion by inhibitor pigments, which are incorporated into the primer coatings of coil-coated architectural cladding. The concentrations of leachate solutions in tubes glu...

3-Methyl-1-phenyl-1,5-dihydro-pyrazolo[3,4-d]pyrimidine-4-thione was prepared and used as a key compound for the preparation of some S-acyclic nucleosides of pyrazolo[3,4d]pyrimidine-thiones. Furthermore, the corrosion inhibitions of the prepared compounds towards carbon steel corrosion by 1.0 M hydrochloric acid were evaluated by chemical and electrochemical methods. The effect of inhibitors c...

The corrosion inhibition characteristics of the derivatives of biopolymer hydroxypropyl methylcellulose (HPMC), hydroxypropyl methylcellulose phthalate (HPMCP), and hydroxypropyl methylcellulose acetate succinate (HPMCAS) film are investigated. Based on electrochemical impedance spectroscopic measurements and potentiodynamic polarization, the corrosion inhibition performance of high speed steel...

A series of new mono-1,2,3-triazole derivatives of pyrimidine nucleobases were synthesized by one-pot copper(I)-catalyzed 1,3-dipolar cycloaddition reactions between N-1-propargyluracil and thymine, sodium azide and several benzyl halides. The desired heterocyclic compounds were obtained in good yields and characterized by NMR, IR, and high resolution mass spectrometry. These compounds were inv...

Recent advances in characterization tools, computational capabilities, and theories have created opportunities for advancement in understanding of solid-fluid interfaces at the nanoscale in corroding metallic systems. The Faraday Discussion on Corrosion Chemistry in 2015 highlighted some of the current needs, gaps and opportunities in corrosion science. Themes were organized into several hierar...