The present invention relates to a nitrogen adsorbent having nitrogen selective adsorptivity by including an organic inorganic hybrid nanoporous material having a coordina tively unsaturated metal site with density of 0.2 mmol/g to 10 mmol/g in a skeleton, Surface or pore; and use thereof, Such as a device separating nitrogen from a gas mixture containing nitrogen and methane, a pressure Swing ...

In this study pre-combustion capture of carbon dioxide from hydrogen was performed using a 5A zeolite adsorber. A one column thermal pressure swing adsorption (TPSA) process was studied in the bulk separation of a CO2/H2 mixture (50:50 vol%). The adsorption dynamics of the zeolite bed were investigated by breakthrough experiments to select the suitable range for operational factors in the desig...

Abstract:  In this study adiffusion based mathematical model was developed to compare the performance of amine-grafted adsorbents with that of 13X zeolite in a fixed-bed adsorption tower which is used to capture CO2 from both humid and dry nitrogen stream under industrial conditions. The results show that the performance of amine-grafted adsorbent and 13X zeolite is almost the same in the dry ...

van der Waals density functional theory (vdW-DFT) and semiempirical grand canonical Monte Carlo (GCMC) calculations are used to predict the thermodynamics and methane storage capacity of 18 metal-substituted variants of the metal−organic framework (MOF) M-DOBDC (DOBDC = 2,5-oxidobenzene-1,4dicarboxylate). Methane adsorption enthalpies (ΔH) on the benchmark Mgand NiDOBDC systems were calculated ...

Nitrogen is among the essential industrial gases after oxygen and hydrogen commonly obtained through air separation process. Air one of gas processes in many chemical industries since it accounts for a substantial element production costs related sectors. In response to this increasing need, most areas investigation quest cost-effective energy-efficient processes. Different technologies nitroge...